Synthesis, spectroscopic, structural, DFT and antibacterial studies of cyclometalated rhodium(III) complex based on morpholinedithiocarbamate ligand

N^N^C-Cyclometalated rhodium(iii) complexes with isomeric pyrimidine-based ligands: unveiling the impact of isomerism on structural motifs, luminescence and cytotoxicity

“…In this manuscript we focus on the investigation of the coordination behaviour of HL 2,5 and HL 2,6 toward rhodium(III) chloride and on unveiling the impact of isomerism on structures and properties. Our particular interest to rhodium complexes stems partly from our experience in rhodium chemistry [82][83][84] and partly from appealing properties this metal shows in the C-H bond activation and catalysis, [85][86][87][88][89][90][91] photochemistry [92][93][94][95][96][97][98][99][100][101][102][103][104][105][106][107] and bioinorganic chemistry. Along with the synthesis of HL 2,5 and HL 2,6 and their rhodium(III) complexes [RhL 2,5 (Solv)Cl 2 ]•nEtOH and [RhL 2,6 (Solv)Cl 2 ]•nEtOH, here we report the impact of isomerism on molecular and supramolecular structures of these compounds, on the photophysical properties of the rhodium(III) complexes and on the cytotoxic activity of the ligands and complexes.…”

Effect of Active Dithiocarbamate Derivatives on Copper Nano Film Deposition

“…But electroless coated articles or samples are very smooth, shiny, more compact and can be achieved in nanoscale deposit (9) . Moreover, the physical, electrochemical, and structural properties of the samples can be modified positively (10) .…”