Synthesis and Characterization of Silver Nanoparticles Using Zinc Chloride-Sugar-Amino Acids Based Novel Ternary Deep Eutectic Solvents

Sarjuna, K

doi:10.1149/10701.4113ecst

ECS Trans.

2022

DOI: 10.1149/10701.4113ecst

|View full text |Cite

Synthesis and Characterization of Silver Nanoparticles Using Zinc Chloride-Sugar-Amino Acids Based Novel Ternary Deep Eutectic Solvents

K Sarjuna

Abstract: In this study, we had effectively generated four types of ternary deep eutectic solvents using the method of evaporation by mixing zinc chloride(ZC) with hydrogen bond donors such as Glucose(GLU) & Fructose(FRU) and Amino acids such as Glutamine(GLUT) & Glycine (GLY) [i.e.a- ZC-GLU-GLY, b- ZC-FRU-GLY, c- ZC-GLU-GLUT, d- ZC-FRU-GLUT]. After that, physical properties such as pH, conductivity, density, and viscosity were applied to the solvents. The H – bonded interaction between zinc chloride and other c… Show more

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2023

Publication Types

Select...

Article3

Relationship

Self Cite0

Independent3

Authors

Journals

Cited by 3 publications

References 30 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Critical Properties of Ternary Deep Eutectic Solvents Using Group Contribution with Extended Lee–Kesler Mixing Rules

et al. 2023

View full text Add to dashboard Cite

One of the most commonly used molecular inputs for ionic liquids and deep eutectic solvents (DESs) in the literature are the critical properties and acentric factors, which can be easily determined using the modified Lydersen–Joback–Reid (LJR) method with Lee–Kesler mixing rules. However, the method used in the literature is generally applicable only to binary mixtures of DESs. Nevertheless, ternary DESs are considered to be more interesting and may provide further tailorability for developing task-specific DESs for particular applications. Therefore, in this work, a new framework for estimating the critical properties and the acentric factor of ternary DESs based on their molecular structures is presented by adjusting the framework reported in the literature with an extended version of the Lee–Kesler mixing rules. The presented framework was applied to a data set consisting of 87 ternary DESs with 334 distinct compositions. For validation, the estimated critical properties and acentric factors were used to predict the densities of the ternary DESs. The results showed excellent agreement between the experimental and calculated data, with an average absolute relative deviation (AARD) of 5.203% for ternary DESs and 5.712% for 260 binary DESs (573 compositions). The developed methodology was incorporated into a user-friendly Excel worksheet for computing the critical properties and acentric factors of any ternary or binary DES, which is provided in the Supporting Information. This work promotes the creation of robust, accessible, and user-friendly models capable of predicting the properties of new ternary DESs based on critical properties, thus saving time and resources.

show abstract

Critical Properties of Ternary Deep Eutectic Solvents Using Group Contribution with Extended Lee–Kesler Mixing Rules

et al. 2023

View full text Add to dashboard Cite

show abstract

Design Strategy and Application of Deep Eutectic Solvents for Green Synthesis of Nanomaterials

et al. 2023

View full text Add to dashboard Cite

The first report of deep eutectic solvents (DESs) was released in 2003 and was identified as a new member of ionic liquid (IL), involving innovative chemical and physical characteristics. Using green solvent technology concerning economical, practical, and environmental aspects, DESs open the window for sustainable development of nanomaterial fabrication. The DESs assist in different fabrication processes and design nanostructures with specific morphology and properties by tunable reaction conditions. Using DESs in synthesis reactions can reduce the required high temperature and pressure conditions for decreasing energy consumption and the risk of environmental contamination. This review paper provides the recent applications and advances in the design strategy of DESs for the green synthesis of nanomaterials. The strategy and application of DESs in wet-chemical processes, nanosize reticular material fabrication, electrodeposition/electrochemical synthesis of nanostructures, electroless deposition, DESs based nano-catalytic and nanofluidic systems are discussed and highlighted in this review.

show abstract

Silver-based SERS substrates fabricated using a 3D printed microfluidic device

Sonexai

Nguyen

Huy

et al. 2023

Beilstein J. Nanotechnol.

View full text Add to dashboard Cite

The detection of harmful chemicals in the environment and for food safety is a crucial requirement. While traditional techniques such as GC–MS and HPLC provide high sensitivity, they are expensive, time-consuming, and require skilled labor. Surface-enhanced Raman spectroscopy (SERS) is a powerful analytical tool for detecting ultralow concentrations of chemical compounds and biomolecules. We present a reproducible method for producing Ag nanoparticles that can be used to create highly sensitive SERS substrates. A microfluidic device was employed to confine the precursor reagents within the droplets, resulting in Ag nanoparticles of uniform shape and size. The study investigates the effects of various synthesis conditions on the size distribution, dispersity, and localized surface plasmon resonance wavelength of the Ag nanoparticles. To create the SERS substrate, the as-synthesized Ag nanoparticles were assembled into a monolayer on a liquid/air interface and deposited onto a porous silicon array prepared through a metal-assisted chemical etching approach. By using the developed microfluidic device, enhancement factors of the Raman signal for rhodamine B (at 10−9 M) and melamine (at 10−7 M) of 8.59 × 106 and 8.21 × 103, respectively, were obtained. The detection limits for rhodamine B and melamine were estimated to be 1.94 × 10−10 M and 2.8 × 10−8 M with relative standard deviation values of 3.4% and 4.6%, respectively. The developed SERS substrate exhibits exceptional analytical performance and has the potential to be a valuable analytical tool for monitoring environmental contaminants.

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Synthesis and Characterization of Silver Nanoparticles Using Zinc Chloride-Sugar-Amino Acids Based Novel Ternary Deep Eutectic Solvents

Cited by 3 publications

References 30 publications

Critical Properties of Ternary Deep Eutectic Solvents Using Group Contribution with Extended Lee–Kesler Mixing Rules

Critical Properties of Ternary Deep Eutectic Solvents Using Group Contribution with Extended Lee–Kesler Mixing Rules

Design Strategy and Application of Deep Eutectic Solvents for Green Synthesis of Nanomaterials

Silver-based SERS substrates fabricated using a 3D printed microfluidic device

Contact Info

Product

Resources

About