Syntheses and Characterization of 2D and 3D Organotin Polymers with Phenylsuccinic Acid and Trimethyltin Chloride Under Different Conditions

Zhang, Rufen; Ren, Yun; Wang, Qingfeng; Ma, Chunlin

doi:10.1007/s10904-010-9330-4

Cited by 16 publications

(6 citation statements)

References 21 publications

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“…It may be inferred that the structures are not affected in the presence of DMSO solvent. The 119 Sn NMR spectra of 1 and 2 are similar to the structure we have previously reported [25].…”

Section: Spectral Characterizationsupporting

confidence: 79%

“…1; selected bond lengths and bond angles for this complex are given in Table 2. The X-ray analysis establishes that 1 is a 1D infinite polymeric chain, which is connected by dimeric tetraorganodistannoxane units as nodes and 3-methyladipic [29]. As shown in (Fig.…”

Section: Crystal Structure Of Complexmentioning

confidence: 82%

“…Etaiw et al have reported a 3D supramolecular coordination polymer containing quinoxaline molecule, multidimensional supramolecular coordination polymers containing triphenyltin cation and CuCN, and a novel 3D-supramolecular coordination polymer based on CuCN, Ph 3 Sn cation and quinoxaline. In our previous work, we have reported several interesting organotin structures derived from multi-ligands through self-assembly, such as six-tin-nuclear 32-member macrocyclic complexes with o-mercaptobenzoic acid [23], a hexanuclear 60-membered macrocyclic complex with 1-(4-carboxyphenyl)-5-mercapto-1H-tetrazole and a 3D organotin polymer with phenylsuccinic acid [24,25].…”

Section: Introductionmentioning

confidence: 99%

“…STS is also a superb technique for crystallizing products that hardly arise from other synthetic methods [26]. In our previous work, we have obtained a 12-member cyclic organotin complex [27], a 1D helical chain [28], a 3D corrugated sheet polymer with (±)-phenylsuccinic acid [29] using the STS method. To continue research in this area, we selected the di carboxylate acid, 3-methyladipic acid, to react with trialkyltin (IV) under different experimental conditions and succeeded in obtaining four new organotin polymers.…”

Section: Introductionmentioning

confidence: 99%

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Syntheses, Characterization and Crystal Structures of 1D and 2D Organotin Polymers Containing 3-Methyladipic Acid Ligand

Zhang

et al. 2011

J Inorg Organomet Polym

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Four new organotin (IV) complexes of two types [(R 2 Sn) 2 (C 7 H 10 O 4 )(l 3 -O)] n (R = Me: 1; nBu: 2; and {(R 3 Sn) 2 [C 5 H 10 (COO) 2 ]} n (R = Me: 3; nBu: 4) have been synthesized by the reaction of 3-methyladipic acid with the corresponding R 3 SnCl (R = Me, nBu) under two different experimental conditions. All the complexes were characterized by elemental analysis, FT-IR, and NMR ( 1 H, 13 C, 119 Sn) spectroscopy. Except for 2, all of the complexes were also characterized by X-ray crystallography. The structural analyzes show that complex 1 is a 1D infinite chain polymer and forms a 2D organotin framework through intermolecular C-HÁÁÁO interactions and weak SnÁÁÁO interactions. Complexes 3 and 4 are 2D network polymers in which 3-methyladipic acid acts as a tetra dentate ligand coordinated to the trialkyltin (IV) ion.

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“…It may be inferred that the structures are not affected in the presence of DMSO solvent. The 119 Sn NMR spectra of 1 and 2 are similar to the structure we have previously reported [25].…”

Section: Spectral Characterizationsupporting

confidence: 79%

Section: Crystal Structure Of Complexmentioning

confidence: 82%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Syntheses, Characterization and Crystal Structures of 1D and 2D Organotin Polymers Containing 3-Methyladipic Acid Ligand

Zhang

et al. 2011

J Inorg Organomet Polym

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“…The coordination geometries of the endo and exo tin atoms are trigonal bipyramidal with the organic groups and one μ 3 -O atom in the equatorial positions, in concordance with previously reported examples . Recently, several research groups have started to explore the utility of these tetranuclear species as secondary building blocks for the generation of porous 2D and 3D coordination polymers. ,,− …”

Section: Resultsmentioning

confidence: 99%

Tuning the Supramolecular Structure through Variation of the Ligand Geometry and Metal Substituents–Diorganotin Macrocycles and Coordination Polymers Derived from cis- and trans-1,2-, 1,3-, and 1,4-Cyclohexanedicarboxylic and cis,cis-1,3,5-Cyclohexanetricarboxylic Acid

Hernández‐Ahuactzi

Cruz‐Huerta

Tlahuext

et al. 2015

Crystal Growth & Design

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cis-and trans-1,2-chdcaH 2 , 1,3-chdcaH 2 , and 1,4-chdcaH 2 (chdcaH 2 = cyclohexanedicarboxylic acid) as well as cis,cis-1,3,5-chtcaH 3 (chtcaH 3 = cyclohexanetricarboxylic acid) have been treated with dimethyl-and di-n-butyltin reagents, and for the case of 1,4-chdcaH 2 additionally with ditert-butyltin dichloride, to determine whether macrocyclic or polymeric diorganotin dicarboxylates are formed dependent of the spatial orientation of the coordinating ligand functions and the organic substituents at the metal atom and to analyze conformational and topological variations in the resulting supramolecular aggregates. The single-crystal X-ray diffraction studies showed that besides the ligand geometry the substituents at the metal center are key elements for the formation of either monomeric, cyclo-oligomeric, or polymeric assemblies. Two of the compounds characterized by X-ray diffraction analysis exhibited macrocyclic ring structures, [{Me 2 Sn(cise,a-1,4-chdca)} 2 ] and [{nBu 2 Sn(cis-e,a-1,4-chdca)} 4 ]. For most of the remaining compounds, one-dimensional polymeric solidstate structures of composition [{R 2 Sn(1,x-chdca)(H 2 O) y } n ] (R = Me, nBu, tBu; x = 2, 3, 4; y = 0, 1) were observed, which had varying topologies, and for the case of the Me 2 Sn and nBu 2 Sn derivatives were further linked to two-or three-dimensional supramolecular architectures, either through intermolecular Sn•••O or O−H•••O hydrogen-bonding interactions.

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Syntheses and Crystal Structures of Di- and Trimethyltin Carboxylates: Ladders and 1D Zig–Zag Chains Polymers

Zhang

Ren

et al. 2011

J Inorg Organomet Polym

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Syntheses and Characterization of 2D and 3D Organotin Polymers with Phenylsuccinic Acid and Trimethyltin Chloride Under Different Conditions

Cited by 16 publications

References 21 publications

Syntheses, Characterization and Crystal Structures of 1D and 2D Organotin Polymers Containing 3-Methyladipic Acid Ligand

Syntheses, Characterization and Crystal Structures of 1D and 2D Organotin Polymers Containing 3-Methyladipic Acid Ligand

Tuning the Supramolecular Structure through Variation of the Ligand Geometry and Metal Substituents–Diorganotin Macrocycles and Coordination Polymers Derived from cis- and trans-1,2-, 1,3-, and 1,4-Cyclohexanedicarboxylic and cis,cis-1,3,5-Cyclohexanetricarboxylic Acid

Syntheses and Crystal Structures of Di- and Trimethyltin Carboxylates: Ladders and 1D Zig–Zag Chains Polymers

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