Syngas Production for Fischer–Tropsch Synthesis from Rubber Wood Pellets and Eucalyptus Wood Chips in a Pilot Horizontal Gasifier with CaO as a Tar Removal Catalyst

Abstract

This research aims to investigate steam biomass gasification in a pilot horizontal gasifier using rubber wood pellets (RWPs) and eucalyptus wood chips (EWCs) for producing syngas with an H 2 /CO ratio range of 1.8 to 2.3 for Fischer−Tropsch synthesis. The study was divided into two parts. One was carried out in a lab-scale reactor to determine the effect of temperature and CaO on the gas product composition and the efficiency of tar removal. Another part was determined by investigating the effect of the steam/biomass (S/B) ratio on the produced H 2 /CO ratios in the pilot horizontal gasifier, which used the optimum conditions of temperature and % loading of CaO for tar removal according to the optimal conditions from the lab-scale gasifier. The lab-scale gasifier results showed that H 2 and CO 2 increased with temperature due to primary and secondary water gas reactions and hydrocarbon reforming reactions. The water gas shift and hydrocarbon reforming reaction depressed the CO and CH 4 contents with increasing temperature, respectively. The optimum gasifying temperature was 900 °C, which obtained H 2 /CO ratios of 1.8 for both RWPs and EWCs. The tar yield decreased with increasing temperature and was less than 0.2 wt % when using CaO as a tar-cracking catalyst. The operation of the pilot horizontal gasifier at the operating condition of 900 °C and a S/B ratio of 0.5 using 0.2 wt % loading of CaO for tar removal also produced a H 2 /CO ratio of 2.0. The supply of an external heat source stabilized the gasifying temperature, resulting in a stable syngas composition and production rate of 2.5 and 2.7 kg/h with H 2 /CO ratios of 1.8 and 1.9 for the RWPs and EWCs, respectively. In summary, the horizontal gasifier is another effective designed gasifier that showed high-performance operation.

Syngas conversion to biofuels and biochemicals: a review of process engineering and mechanisms

“…The gasification process of these various types of feedstocks is executed in a gasifier at high pressure and temperature in the presence of gasifying agents, including oxygen or steam. 1 According to one study, the estimated production of syngas is approximately 598 million tons per year. 2 Apart from the thermal gasification process, syngas is generated as a waste gas from the chemical and steel industry, and its composition is influenced by a number of parameters, such as the type of gasifier and operational conditions.…”