“…Metal-organic frameworks (MOFs) have shown satisfactory results and prospects in many fields due to their excellent chemical functionality, modifiable morphology, pore structure and high specific surface area. MOF materials are now widely used in electrochemistry [18], adsorption [19], separation [20], multiphase catalysis [21], and drug delivery [22]. Among them, MIL-100(Fe) is used as a transition metal MOF, which has two different mesoporous cages (2.5 and 2.9 nm).…”
“…Metal-organic frameworks (MOFs) have shown satisfactory results and prospects in many fields due to their excellent chemical functionality, modifiable morphology, pore structure and high specific surface area. MOF materials are now widely used in electrochemistry [18], adsorption [19], separation [20], multiphase catalysis [21], and drug delivery [22]. Among them, MIL-100(Fe) is used as a transition metal MOF, which has two different mesoporous cages (2.5 and 2.9 nm).…”
“…According to the aforementioned findings, the surface adsorption controlled the electrochemical responses between DA and UA on the ZnO-CeO 2 /GCE electrode. The electro-oxidation reactions of DA and UA on ZnO-CeO 2 /GCE are a two-electron-transfer process, and the reaction mechanisms can be expressed as follows [37]: = 15.5942υ + 0.2405 (R 2 = 0.994). According to the aforementioned findings, the surface adsorption controlled the electrochemical responses between DA and UA on the ZnO-CeO2/GCE electrode.…”
Section: Electrochemical Performance Of Zno-ceo 2 Hollow Nanospheresmentioning
confidence: 99%
“…According to the aforementioned findings, the surface adsorption controlled the electrochemical responses between DA and UA on the ZnO-CeO2/GCE electrode. The electro-oxidation reactions of DA and UA on ZnO-CeO2/GCE are a two-electron-transfer process, and the reaction mechanisms can be expressed as follows [37]:…”
Section: Electrochemical Performance Of Zno-ceo 2 Hollow Nanospheresmentioning
ZnO-CeO2 hollow nanospheres have been successfully synthesized via the hard templating method, in which CeO2 is used as the support skeleton to avoid ZnO agglomeration. The synthesized ZnO-CeO2 hollow nanospheres possess a large electrochemically active area and high electron transfer owing to the high specific surface area and synergistic effect of ZnO and CeO2. Due to the above advantages, the resulting ZnO-CeO2 hollow spheres display high sensitivities of 1122.86 μA mM−1 cm−2 and 908.53 μA mM−1 cm−2 under a neutral environment for the selective detection of dopamine and uric acid. The constructed electrochemical sensor shows excellent selectivity, stability and recovery for the selective analysis of dopamine and uric acid in actual samples. This study provides a valuable strategy for the synthesis of ZnO-CeO2 hollow nanospheres via the hard templating method as electrocatalysts for the selective detection of dopamine and uric acid.
“…A composite was prepared including PMo 12 O 40 3− (PMo 12 ) as polyoxmetalate (POM), C 9 H 5 FeO 7 (MIL-100(Fe) as an Fe-based MOF, and polyvinylpyrrolidone (PVP), and then it was deposited on a GCE for the simultaneous determination of DA and UA [ 79 ]. MIL-100(Fe) can encapsulate POMs within its mesoporous architecture.…”
Section: Applications Of 2d Nanomaterials To Electrochemical (Bio)sen...mentioning
Two-dimensional (2D) nanomaterials (e.g., graphene) have attracted growing attention in the (bio)sensing area and, in particular, for biomedical applications because of their unique mechanical and physicochemical properties, such as their high thermal and electrical conductivity, biocompatibility, and large surface area. Graphene (G) and its derivatives represent the most common 2D nanomaterials applied to electrochemical (bio)sensors for healthcare applications. This review will pay particular attention to other 2D nanomaterials, such as transition metal dichalcogenides (TMDs), metal–organic frameworks (MOFs), covalent organic frameworks (COFs), and MXenes, applied to the electrochemical biomedical (bio)sensing area, considering the literature of the last five years (2018–2022). An overview of 2D nanostructures focusing on the synthetic approach, the integration with electrodic materials, including other nanomaterials, and with different biorecognition elements such as antibodies, nucleic acids, enzymes, and aptamers, will be provided. Next, significant examples of applications in the clinical field will be reported and discussed together with the role of nanomaterials, the type of (bio)sensor, and the adopted electrochemical technique. Finally, challenges related to future developments of these nanomaterials to design portable sensing systems will be shortly discussed.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.