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N-doping is one of the most promising strategies to improve the adsorption capacity and selectivity of carbon adsorbents. Herein, synthesis, characterization and dye adsorption of a novel N-doped microporous biochar derived from direct annealing of crop straws under NH3 is presented. The resultant products exhibit high microporosity (71.5%), atomic percentage of nitrogen (8.81%), and adsorption capacity to dyes, which is about 15-20 times higher than that of original biochar. Specifically, for the sample NBC800-3 pyrolyzed at 800°C in NH3 for 3 h, its adsorption for acid orange 7 (AO7, anionic) and methyl blue (MB, cationic) is up to 292 mg g(-1) and 436 mg g(-1), respectively, which is among the highest ever reported for carbonaceous adsorbents. The influences of N-doping and porous structure on dye adsorption of the synthesized carbons are also discussed, where electrostatic attraction, π-π electron donor-accepter interaction, and Lewis acid-base interaction mainly contribute to AO7 adsorption, and surface area (especially pore-filling) dominates MB adsorption. The N-doped biochar can be effectively regenerated and reused through direct combustion and desorption approaches.

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Understanding changes in habitat quality and the driving forces of these changes at landscape scales is a critical part of effective ecosystem management. The present study investigated spatiotemporal habitat quality dynamics and related driving forces from 2005 to 2015 in the upper basin of Miyun Reservoir in North China by constructing an effective framework integrated InVEST and binary logistic regression models. This framework expanded the driving force analysis into an assessment of changes in habitat quality and intuitively verified the effectiveness of relevant environmental policies. The proposed method of combining the equidistant random sampling method and the method of introducing spatial lag variables in logistic regression equation can effectively solve spatial autocorrelation with a large enough number of sampling points. Overall, habitat quality improved during the study period. Spatially, a concentrated loss of habitat occurred in the southeastern part of the basin between the reservoir and mountainous areas, while other areas gradually recovered. Driving force analysis showed that lower elevation mountain land, gentle slopes, locations near rural land or roads, larger areas of grain cultivation, and areas with little population change had a higher likelihood of having changed in habitat quality in the upper basin of Miyun Reservoir. These results suggested that the present policy of protecting the ecosystem had a positive effect on improving habitat quality. In the future, the human activity management related to habitat quality needs to be strengthened. The present study would provide a reference for land use policy formulation and biodiversity conservation.

A free-radical halotrifluoromethylation of olefins by using Mn-(OAc) 3 •2H 2 O, CF 3 SO 2 Na, and perhalogenated carboxylic acids has been achieved. Perhalogenated carboxylic acids act as a halogen source and CF 3 SO 2 Na acts as a CF 3 source. The reaction displayed good tolerance of functional groups in the substrates under mild conditions. The radical clock experiment and TEMPO inhibition experiment support a radical process. The halogen reagent competition experiment shows that the last step of halogenation process is mainly through a halogen abstraction mechanism.

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