Surface treatment of polymer matrix nanocomposites for adhesion enhancement by cold plasma

Berczeli, Miklós; Hatoss, B; Kókai, E

doi:10.1088/1757-899x/1246/1/012028

Cited by 3 publications

(1 citation statement)

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“…Several studies investigated PP/MWCNT nanocomposites by rheological, thermal, and mechanical methods, but just a few determined zero-shear-rate viscosity in a wide temperature range, melting and crystallization behaviors, and mechanical properties of recycled PP/MWCNT nanocomposites. In a number of manufacturing technology areas, the re-use of recycled raw materials is increasingly demanded [ 24 ]. Recycled PP nanocomposites may be suitable for multiple uses, without significantly increasing the environmental impact of their production and can also contribute to the development of a circular economy.…”

Section: Introductionmentioning

confidence: 99%

Effect of Recycling on the Mechanical, Thermal and Rheological Properties of Polypropylene/Carbon Nanotube Composites

2022

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In this research the effect of physical recycling on the mechanical, thermal, and rheological properties of polypropylene (PP)/multiwalled carbon nanotube (MWCNT) was investigated. After melt homogenization by extrusion, specimens were injection moulded with 0.1 and 0.5 wt% MWCNT content. The recycling process was simulated by multiple grinding and re-moulding, then we compared the behavior of original and recycled PP/MWCNT composites. Differential scanning calorimetry (DSC) measurements proved that MWCNT had double the effect on the morphology of the PP matrix: on the one hand nucleating effect can be detected because 0.5 wt% MWCNT increased the onset temperature of crystallization by 10°C, compared to the basic PP material; on the other hand, the crystalline fraction of the recycled composite materials decreased compared to the original PP material with the same MWCNT content. This resulted in a slight decrease in strength and stiffness but an increase in elongation at break. However, compared to the original unreinforced PP reference, even the recycled materials have better properties. The mechanical test results showed that recycled PP/MWCNT 0.5 wt% increased the elastic modulus (~15%) and decreased the tensile strain at yield (~10%). However, in the values of tensile stress at yield, relevant difference was not found. It was also shown by oscillatory rheometry that MWCNT had a significant effect on the rheological properties (storage and loss modulus, complex viscosity) of PP compounds in a wide temperature range (190–230 °C).

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Section: Introductionmentioning

confidence: 99%