Recently, rapid advancements in epitaxial layer growth technologies have made possible the fabrication of several types of quantum structures [I to 31. Among these structures, coupled quantum wells have been attractive because of the interest in the investigation of both the fundamental physical properties [4 to 61 and tunable coherent light sources for optical communications resulting from the enhancement of the Stark effect [7 to 91. Although the basic physical principles for such quantum structures have been introduced in quantum mechanics texts for many years (see, for example, [lo]), the corresponding experimental results have not yet been obtained because of the delicate problems encountered in the growth techniques. Potential applications of 11-VI compound semiconductors in optoelectronics have driven an extensive and successful effort to grow CdTe and ZnTe on various substrates [ll to 151. Although a few works concerning coupled quantum wells have been reported [8, 91, to the best of our knowledge, only the results for the GaAs/Al,Ga,-,As system have been reported: the coupling behavior of 11-VI/II-VI symmetric and asymmetric double quantum wells has not been reported yet. Among these structures, the CdTe/ZnTe structure is particularly interesting due to its many possible optical applications [16].This note reports interband transitions of CdTe/ZnTe symmetric and asymmetric double quantum wells (DQW) grown by double-well temperature-gradient vapor-transport deposition (DWTGVTD). Photoluminescence (PL) measurements were carried out to investigate the interband transitions of the CdTe/ZnTe DWQs, and the electronic subband energies and the wave functions in the quantum wells were calculated taking into account strain effects.Polycrystalline stoichiometric CdTe and ZnTe with a purity of 99.9999% grown by the Bridgman method were used as source materials and were precleaned by repeated sublimation. A Cr-doped semi-insulating GaAs substrate was degreased in warm trichloroethylene (TCE), rinsed thoroughly in deionized water, etched in a HF solution, and rinsed in TCE again. As soon as the chemical cleaning process was finished, the wafers were mounted on a molybdenum susceptor. Before the CdTe/ZnTe double quantum well growth, the GaAs substrates were thermally cleaned at 600 "C for 5 min in situ in a growth chamber at a pressure of lo-' Torr. The deposition was done at a substrate temperature of 300 "C I ) 447-1 Wolgye-dong, Nowon-ku, Seoul 139-701, Korea. ' ) Seoul 120-749, Korea.