Structural and magnetic properties of one-dimensional coordination polymers {trans-[Ru(CN-tBu)4(CN)2]FeX3}n vs. molecular squares {cis-[Ru(CN-tBu)4(CN)2]FeX3}2 (X=NO3, Cl)

Halbauer, Kathi; Spielberg, Eike T.; Sterzik, Anke; Plass, Winfried; Imhof, Wolfgang

doi:10.1016/j.ica.2009.12.021

Cited by 16 publications

(1 citation statement)

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“…To date, only a few such examples have been reported. [32][33][34][35][36][37][38][39][40] Recently, our group has been interested in the investigation of polynuclear compounds with a bridging diamagnetic cyanidometal ligand. [41][42][43][44][45][46][47] In this paper, we report the syntheses, crystal structures, electronic absorption spectroscopy and magnetic properties of two tetra-nuclear cyanide-bridged square complexes [cis-Fe(bpy)…”

Section: Introductionmentioning

confidence: 99%

Syntheses, crystal structures and magnetic properties of two heterometallic cyanide-bridged [MII2MnII2] (M = Fe and Os) square complexes

et al. 2016

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Two tetra-nuclear cyanide-bridged square complexes [cis-Fe(bpy) 2 (CN) 2 Mn(L)] 2-[PF 6 ] 4 (1) and [cis-Os(bpy) 2 (CN) 2 Mn(L)] 2 [PF 6 ] 2 [ClO 4 ] 2 (2) (bpy = 2, 2'-bipyridine, L = 1,6-diphenyl-2,5-bis(2-methylpyridyl)-2,5-diazahexane) were synthesized and fully characterized. The tetranuclear [cis-M(bpy) 2 (CN) 2 Mn(L)] 2 4+ (M = Fe (1), Os (2)) cation is composed of two [M(bpy) 2 (CN) 2 ] and two [Mn(L)] 2+ centers. Each M II ion adopts a distorted [MN 4 C 2 ] octahedral coordination, surrounding by four nitrogen atoms from two bpy ligands and two carbon atoms from the cyanide groups in a cis position. Each Mn 2+ ion

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Section: Introductionmentioning

confidence: 99%

Syntheses, crystal structures and magnetic properties of two heterometallic cyanide-bridged [MII2MnII2] (M = Fe and Os) square complexes

et al. 2016

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Synthesis of Trinuclear Heterobimetallic Cyanido‐Bridged Complexes from the Reaction of [Mn^I(CN)(CO)(tBuNC)₄] with Transition‐Metal Chlorides

et al. 2014

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The reaction of [Mn(CN)(CO)(tBuNC)4] with MnCl2·4H2O, FeCl3·9H2O, NiCl2·6H2O, and CuCl2·2H2O, respectively, led to the formation of trinuclear heterobimetallic complexes that comprised two manganese moieties, with each coordinating the corresponding metal chloride entities through cyanide bridges. The mixed‐valence trinuclear MnI–CN–MnII–NC–MnI complex as well as the MnI–CN–NiII–NC–MnI derivative have been characterized by X‐ray structure analyses. In the case of the copper and iron compounds that exhibit easily reducable central metal ions, intramolecular electron transfer from manganese(I) to copper(II) or iron(III), respectively, is shown by the presence of metal‐to‐metal charge‐transfer (MMCT) bands as well as by EPR spectroscopy. Moreover, the iron complex shows a subsequent disproportionation, which was demonstrated by the isolation and crystallographic characterization of the reduced species with two manganese(I) complex units coordinating one FeIICl2 moiety.

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Magnetic properties of cyano-bridged bimetallic Ru(II)-Fe(III) polymeric complex with t-butyl isocyanide and chloride ligands

Pardasani

2022

Magnetic Properties of Paramagnetic Compounds, Magnetic Susceptibility Data, Volume 6

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Structural and magnetic properties of one-dimensional coordination polymers {trans-[Ru(CN-tBu)4(CN)2]FeX3}n vs. molecular squares {cis-[Ru(CN-tBu)4(CN)2]FeX3}2 (X=NO3, Cl)

Cited by 16 publications

References 91 publications

Syntheses, crystal structures and magnetic properties of two heterometallic cyanide-bridged [MII2MnII2] (M = Fe and Os) square complexes

Syntheses, crystal structures and magnetic properties of two heterometallic cyanide-bridged [MII2MnII2] (M = Fe and Os) square complexes

Synthesis of Trinuclear Heterobimetallic Cyanido‐Bridged Complexes from the Reaction of [Mn^I(CN)(CO)(tBuNC)₄] with Transition‐Metal Chlorides

Magnetic properties of cyano-bridged bimetallic Ru(II)-Fe(III) polymeric complex with t-butyl isocyanide and chloride ligands

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Structural and magnetic properties of one-dimensional coordination polymers {trans-[Ru(CN-tBu)4(CN)2]FeX3}n vs. molecular squares {cis-[Ru(CN-tBu)4(CN)2]FeX3}2 (X=NO3, Cl)

Cited by 16 publications

References 91 publications

Syntheses, crystal structures and magnetic properties of two heterometallic cyanide-bridged [MII2MnII2] (M = Fe and Os) square complexes

Syntheses, crystal structures and magnetic properties of two heterometallic cyanide-bridged [MII2MnII2] (M = Fe and Os) square complexes

Synthesis of Trinuclear Heterobimetallic Cyanido‐Bridged Complexes from the Reaction of [MnI(CN)(CO)(tBuNC)4] with Transition‐Metal Chlorides

Magnetic properties of cyano-bridged bimetallic Ru(II)-Fe(III) polymeric complex with t-butyl isocyanide and chloride ligands

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Synthesis of Trinuclear Heterobimetallic Cyanido‐Bridged Complexes from the Reaction of [Mn^I(CN)(CO)(tBuNC)₄] with Transition‐Metal Chlorides