Electric force microscopy (EFM)-based
methods have the capacity to probe surface potential, dielectric properties,
and surface charges. It can be robustly used for analyzing charge-transfer
mechanisms in nanostructures by measuring the electrostatic forces
between a sample surface and a tip. The highest achievable resolution
for conventional EFM under ambient conditions is defined mainly by
the tip–sample separation d, which is limited
by the “jump-to-contact” effect. In this paper, the
contact-resonance EFM methodology operating at close to zero d is demonstrated, which is applicable to semiconductors,
metals, and dielectrics. Being implemented at the contact resonance
frequency of the atomic force microscopy probe in contact with the
surface, it allows an improvement in the sensitivity and boosting
of the signal-to-noise ratio and it enables the condition required
for high-resolution imaging. Furthermore, the critical role of nonconducting
organic compounds to achieve a smaller d, and subsequently
enhancing the electrostatic signal, is addressed.