Individually, ferrocene and photochromic materials have several important attributes and applications. Ferrocene is a promising candidate of stimuliresponsive materials due to its electronic, electrochemical and magnetic properties. On the same lines, photo-sensitive materials are also an important class of stimuli-responsive materials which can be modified according to the needs.Recently, a lot of keen attention has been given to the combination of ferrocene with different photo-sensitive moieties to get novel functional materials. This review illustrates the research advances in the combination of ferrocene-based small molecules, self-assembled monolayers and polymers with photo-responsive compounds and their potential applications.