1993
DOI: 10.1103/physrevb.48.11833
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Spontaneous ordering inGaInP2: A polarized-piezomodulated-reflectivity study

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Cited by 57 publications
(18 citation statements)
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“…3,4,6 Such ordering both lowers the band-gap energy and splits the quadruply degenerate valence band states. These ordering-induced electronic structure changes have been well established by photoluminescence ͑PL͒, 2,6 photoluminescence excitation, 7,8 and polarized piezomodulation 5 spectroscopies as well as more recent exciton absorption bleaching measurements. 9 First-principles and perturbation based electronic structure calculations agree well with these experiments.…”
Section: Introductionmentioning
confidence: 77%
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“…3,4,6 Such ordering both lowers the band-gap energy and splits the quadruply degenerate valence band states. These ordering-induced electronic structure changes have been well established by photoluminescence ͑PL͒, 2,6 photoluminescence excitation, 7,8 and polarized piezomodulation 5 spectroscopies as well as more recent exciton absorption bleaching measurements. 9 First-principles and perturbation based electronic structure calculations agree well with these experiments.…”
Section: Introductionmentioning
confidence: 77%
“…The PL spectra for the 1000 Å and 1 m thick samples both show a clear polarization dependence and are peaked at lower energy than that for disordered GaInP 2 , ϳ2.0 eV. 5,8 Specifically, the PL spectra are peaked at 1.901 and 1.886 eV with polarized intensity ratios of 1.91 and 2.44 for the 1000 Å and 1 m samples, respectively. For GaInP 2 layers ordered along the ͓111͔ direction, a decreased band-gap energy along with stronger PL polarized along ͓110͔, the projection of the ͓111͔ ordering direction onto the ͓001͔ sample surface, is expected.…”
Section: Methodsmentioning
confidence: 88%
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“…The lattice symmetry of an ordered alloy reduces from T d (totally disordered) to C 3v (perfectly ordered CuPt-B) [8]. Atomic ordering in the CuPt-B lattice causes many changes in the electronic and optical properties of the III-V semiconductor alloys such as valence band splitting [9], bandgap reduction [10], optical anisotropy [11], second-harmonic generation [12], birefringence [13], and conductivity anisotropy [14]. The degree of ordering in an epitaxial semiconductor film is found to be dependent on the growth conditions.…”
Section: Introductionmentioning
confidence: 99%
“…[1][2][3][4][5][6][7][8][9][10] The long-range ordering of the column III sublattice appears in Ga 0.5 In 0.5 P epitaxial films grown on GaAs ͑001͒ by organometallic vapor-phase epitaxy ͑OM-VPE͒. The epitaxial alloys consist of two ordered phases that show the CuPt-like ordering along the ͓111͔ and ͓111͔, i.e., ͓111͔ and ͓111͔ monolayer superlattices ͑MSLs͒.…”
mentioning
confidence: 99%