Sulphur (S) deficiency is widespread in Indian soils, and it has been emerging as a major problem in rice-growing lateritic soils of West Bengal. The vertical distribution of S forms and their relationships with soil physicochemical properties were examined in 50 rice-growing locations of lateritic soils of West Bengal, India, for the current study. For this a total of one hundred fifty representative soil samples were collected from three depths and fifty representative locations of rice-based cropping systems of lateritic belt of West Bengal and analyzed for different fractions of S and important physicochemical properties using standard methodology. Most soils were sandy clay loam to clay loam, with low to medium levels of organic carbon, and strongly acidic to moderately acidic. A decrease in organic carbon across the depths was evident. Among the sulphur forms, organic S was dominant, and the contribution of water-soluble S was least throughout the soil profile. The studied sulphur forms followed the order: total S > organic S > heat soluble S > adsorbed S > sulphate S > water soluble S. Except for adsorbed S, most forms decreased with soil depth. The correlation study revealed that soil pH was positively and significantly correlated with water soluble (r = 0.431**) and sulphate S (r = 0.325*) in surface soils, with sulphate S both in mid-surface (r = 0.450**) and subsurface soils (r = 0.423**). Organic carbon showed a positive correlation with all the S forms throughout the profile. Both clay and silt content positively affected S forms, while sand content showed a negative relationship. Positive correlation among all the S forms observed along soil depth, except for a negative correlation between adsorbed S and sulphate S. This investigation will be helpful for sulphur management to optimize crop yields in lateritic soils.