Some Reactions of 2,6-Dialkylphenols<sup>1</sup>

Coffield, T. H.; Filbey, Allen H.; Ecke, George G.; Kolka, Alfred J.

doi:10.1021/ja01575a051

Cited by 63 publications

(14 citation statements)

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“…This change in properties is particularly pronounced in 2,6-di-tert-alkylphenols [23]. The alkyl groups themselves can also show typical reactions.…”

Section: Chemical Propertiesmentioning

confidence: 93%

Phenol Derivatives

Fiege

Voges²,

Hamamoto

et al. 2000

Ullmann's Encyclopedia of Industrial Chemistry

187

175

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The article contains sections titled: 1. Alkylphenols 1.1. Physical Properties 1.2. Chemical Properties 1.3. Occurrence, Formation, Isolation 1.4. Production, General 1.4.1. Alkylation of Phenols 1.4.2. Other General Processes 1.5. Industrially Important Alkylphenols 1.5.1. Polymethylphenols 1.5.2. Ethylphenols 1.5.3. Isopropylphenols 1.5.4. sec ‐Butylphenols 1.5.5. tert ‐Butylphenols 1.5.6. tert ‐Pentylphenols 1.5.7. Higher Alkylphenols 1.5.8. Cycloalkylphenols 1.5.9. Aralkylphenols 1.5.10. Alkenylphenols 1.5.11. Indanols 2. Catechol 2.1. Physical Properties 2.2. Chemical Properties 2.3. Production 2.4. Uses 2.5. Economic Aspects 2.6. Toxicology 3. Trihydroxybenzenes 3.1. Pyrogallol 3.2. Hydroxyhydroquinone 3.3. Phloroglucinol 4. Bisphenols (Bishydroxyarylalkanes) 4.1. Physical Properties 4.2. Chemical Properties 4.3. Production 4.4. Analysis, Testing, Storage 4.5. Uses, Economic Aspects 4.6. Toxicology 5. Hydroxybiphenyls 5.1. Physical Properties 5.2. Chemical Properties 5.3. Production 5.4. Analysis, Quality Specifications, Storage 5.5. Uses 5.6. Toxicology 6. Phenol Ethers 6.1. Properties 6.2. Production 6.3. Representative Phenol Ethers 7. Halogen Derivatives of Phenolic Compounds 7.1. Introduction 7.2. Representative Compounds

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“…This change in properties is particularly pronounced in 2,6-di-tert-alkylphenols [23]. The alkyl groups themselves can also show typical reactions.…”

Section: Chemical Propertiesmentioning

confidence: 93%

Phenol Derivatives

Fiege

Voges²,

Hamamoto

et al. 2000

Ullmann's Encyclopedia of Industrial Chemistry

187

175

View full text Add to dashboard Cite

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“…To form the second substrate for the planned olefination, 14 was oxidized with Br 2 in tert-butanol to produce the aldehyde 15. [14] A Wittig reaction between 13 and 15 in toluene at reflux afforded the E stilbene 16 in good yield; it was not necessary to protect the phenolic hydroxy group of 15. Finally, the benzyl protecting groups were removed [4] from 16 to give the coupling precursor 17 in 53 % overall yield.…”

mentioning

confidence: 99%

Total Synthesis of (±)‐Quadrangularin A

Liu

et al. 2006

Angew Chem Int Ed

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“…10 Treating 5 with malonate in the presence of pyridine and piperidine afforded the coupling precursor 6 in 81% yield. Oxidation of 6 with FeCl 3 /O 2 gave b-b-coupling product dilactone 7 in high yield (91%), 5,11 which validated our initial thought.…”

Section: Lettermentioning

confidence: 99%

Regioselective Oxidative Coupling Approach to the Synthesis of (±)-Matairesinol and (±)-Secoisolariciresinol

Zhu¹,

Li²,

Wang³

et al. 2006

Synlett

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Some Reactions of 2,6-Dialkylphenols¹

Cited by 63 publications

References 0 publications

Phenol Derivatives

Phenol Derivatives

Total Synthesis of (±)‐Quadrangularin A

Regioselective Oxidative Coupling Approach to the Synthesis of (±)-Matairesinol and (±)-Secoisolariciresinol

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Some Reactions of 2,6-Dialkylphenols1

Cited by 63 publications

References 0 publications

Phenol Derivatives

Phenol Derivatives

Total Synthesis of (±)‐Quadrangularin A

Regioselective Oxidative Coupling Approach to the Synthesis of (±)-Matairesinol and (±)-Secoisolariciresinol

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Product

Resources

About

Some Reactions of 2,6-Dialkylphenols¹