“…Chalcogenides and pnictides based ternary tetrahedral (A II B IV C 2 V and A I B III C 2 VI ) semiconductors, which build a broader class of semiconducting materials with varied structural, mechanical, electrical, and optical properties and have attracted interest because of their growing scientific and technological applications. Among complex solids, ternary compounds are semiconductors having a large energy direct band gap, strong non linearity, low thermal conductivity, broad transparency window, lower melting temperatures, and a tetragonal chalcopyrite crystal structure [1][2][3][4][5][6]. Once studied for their low thermal conductivities, currently they are investigated for applications like as electromagnetic (EM) screening, spintronics [7][8], and photovoltaics [9].…”