Siliciummonoxyd

Organosilicon Derivatives of Sulfur

“…65,104,211,377,403,489,552,703,704]. It is formed by high temperature reactions 'of silicon with sulfur [189,326,332,378,470,571,582,595,596,644,693]; silicon with hydrogen sulfide [595,596,597,685]; silicates and Si0 2 with CS 2 [326,327,[334][335][336][337]450, 685], sulfur [708], and a mixture of S2Cl2 with chlorine [191]; Si0 2 with hydrogen sulfide in the presence of charcoal [685]; lithium, calcium, copper, magnesium, and iron sUicides with sulfur [188,244,489,506,507]; SiO with S02 [736]; and sulfides of iron [141,293,576,738] and aluminum [192,193,420,421,423,636,642,[685][686]…”

IR laser-induced carbothermal reduction of silicon monoxide

“…It is only known that silicon monoxide is easily oxidized [16,17], reacts with aqueous HF to Si and polysilanes [18], it is degraded by alkaline glycolates to pentacoordinated silicon compounds [19] and reduced by Mg to MgSi 2 [13].…”

Elemental silicon and solid SiO give the same products as SiO2 upon reaction with alkali-metal glycolates

“…In all the other known reactions, SiO was used as a reductant, with the concomitant formation of Si IV compounds. [3][4][5][6] One of the few straightforward reactions of SiO 2 leading to molecular compounds is its reaction with alkali-metal hydroxide and ethylene glycol by which To compare the reactivity of solid SiO with that of SiO 2 , we reacted SiO powder † with a solution of lithium or sodium ethylene glycolate in ethylene glycol at T > 140 ЊC. ‡ The glycolate was prepared by reacting one to three molar equivalents of the alkali-metal (relative to SiO) with the glycol.…”