Organosilicon Derivatives of Sulfur

Borisov, S. N.; Воронков, М. Г.; Лукевиц, Э.

doi:10.1007/978-1-4684-0727-3_2

Cited by 3 publications

(1 citation statement)

References 470 publications

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“…Interestingly, 8 features highly electrophilic silicon atoms that readily react with a variety of nucleophiles. [23] Accordingly, 8 reacted with sodium formate to give silyl formate 2 b isolated in 70 % yield (92 % purity), after separation from the solid by-product Na 2 SO 4 and the dibutyl ether solvent by distillation.…”

Section: Angewandte Chemiementioning

confidence: 99%

Catalytic Disproportionation of Formic Acid to Methanol by using Recyclable Silylformates

et al. 2020

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A novel strategy to prepare methanol from formic acid without external reductant is presented. The overall process described herein consists in the disproportionation of silyl formates to methoxysilanes catalyzed by ruthenium complexes and the production of methanol thereof by simple hydrolysis. Aqueous solutions of MeOH (> 1 mL, > 70 % yield) were prepared in this manner. The sustainability of the reaction has been established by the recycling of the silicon-containing byproducts with cheap, readily available and environmentally-benign reagents.

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Section: Angewandte Chemiementioning

confidence: 99%