S5N5[SnCl5(CH3CN)]; Synthese, IR-Spektrum, 119Sn-Mößbauer-Spektrum und Kristallstruktur / S5N5[SnCl5(CH3CN)]; Synthesis, IR Spectrum , Mössbauer Spectrum and Crystal Structure

Patt‐Siebel, U.; Ruangsuttinarupap, S.; Müller, Ulrich; Pebler, J.; Dehnicke, Kurt

doi:10.1515/znb-1986-1001

Cited by 17 publications

(5 citation statements)

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“…For background to halogentin(IV) chemistry, see: Hausen et al (1986); Koutsantonis et al (2003); Mahon et al (2004); Patt-Siebel et al(1986); Szymanska-Buzar et al (2001); Tudela et al (1986). For tin compounds containing an Sn-Cl bond in a cisor trans-position, see: Fernandez et al (2002); Hazell et al (1998); Sow et al (2010).…”

Section: Related Literaturementioning

confidence: 99%

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Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate

et al. 2013

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The SnIV atom in the title compound, [(CH3)4N][Sn(C2O4)Cl3(H2O)]·H2O, obtained from the reaction between SnCl4 and [(CH3)4N]2C2O4·2H2O, is six-coordinated by three Cl atoms, an O atom of a water molecule and two O atoms from an asymmetrically chelating oxalate anion. The environment around the SnIV atom is distorted octahedral. The anions are connected by the lattice water molecule through O—H⋯O hydrogen bonds, leading to a layered structure parallel to (010). The cations are located between these layers and besides Coulombic forces are connected to the anionic layers through weak C—H⋯O and C—H⋯Cl interactions.

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Section: Related Literaturementioning

confidence: 99%

“…of SnX 4 adducts (X = halogen) containing tin(IV) in an octahedral environment have been reported up to date, e.g Hausen et al (1986)Koutsantonis et al (2003);Mahon et al (2004);Patt-Siebel et al (1986);Szymanska-Buzar et al (2001);…”

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confidence: 99%

Tetramethylammonium aquatrichloridooxalatostannate(IV) monohydrate

et al. 2013

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“…[SMe 3 ][SnBr 5 (MeCN)], see Figure , crystallizes in the space group P 2 1 / n with a C 4 v symmetry around the Sn atom and has similarities to the structures of [(Ph 3 As) 2 CCN(SnBr 5 )] and the chlorinated isomorph [S 5 N 5 ][SnCl 5 (MeCN)] . The Sn–Br bond distances vary between 253.7(1) and 258.8(1) pm.…”

Section: Resultsmentioning

confidence: 92%

“…For [SnBr 5 (MeCN)] − , the angles Br1–Sn1–Br3 (168.2(1)°) and Br1–Sn1–Br5 (95.6(1)°) indicate a repulsive Br–Br interaction toward the acetonitrile group. The angle of Sn1–N1–C1 was 155.4(1)° as opposed to that of [SnCl 5 (MeCN)] − with a more obtuse angle of 168.4(4)° …”

Section: Resultsmentioning

confidence: 99%

Synthesis, Crystallization, and Electrochemical Characterization of Room Temperature Ionic Liquid Bromidostannates(II/IV)

et al. 2021

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Ionic liquids (IL) are valuable in a variety of applications due to their high electrochemical stability and physical properties. Using the cation 1-methyl-3-octylimidazolium, [OMIM] + , the bromidostannate RTIL [OMIM][Sn +II Br 3 ], "undercooled melt" [OMIM][Sn +IV Br 5 ], and IL [OMIM] 2 [Sn +IV Br 6 ] were synthesized. The uncommon solid state structure of [SnBr 5 ] − was elucidated in the form of its RTIL salt. Additionally, the IL based on tribromine-monoanion [OMIM][Br 3 ] was used to dissolve metallic Sn, selectively resulting in the formation of [SnBr 3 ] − as confirmed by Raman spectroscopy. Subsequent cyclic voltammograms (CV) of [SnBr 3 ] − confirmed the deposition potential of metallic Sn and renewal of the polybromide [Br 3 ] − . The RTIL bromidostannates were stable compounds, making a selective electrochemical investigation of the deposition of metallic Sn(0) to Sn(+II)/Sn(+IV) redox process possible, via conductance and CV measurements. The CVs of the RTILs and of solutions in propylene carbonate had the redox couples of Sn(0)/

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“…Die Summe der Bindungswinkel am Bru È cken-C-Atom C(101) betra Ègt 360,0°, entsprechend sp 2 -Hybridisierung. Zusammen mit der gestreckten Achse C(101)±C(102)±N(101) und des gegenu È ber einer C±C-Einfachbindung (153±156 pm [18]) auf 141,6 pm verku È rzten Abstandes C(101)±C(102) und des mit einer C ≡ N-Dreifachbindung (116 pm [18]) vergleichbaren Abstandes C(102)±N (101) [19,20]. Die Bindungsla È ngen Sn±Br liegen zwischen 254,5 und 259,3 pm.…”

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