h i g h l i g h t sThe effects from hemispherical/regional aircraft NO x emissions are explored using 3D CTM, MOZART-3. The climate metrics values decrease with increasing regional aircraft NO x emission rates, except for Southeast Asia. Regional applications of an equal mass and a relative mass of aircraft NO x emission result in different regional dependencies. The greatest net NO x radiative forcing is observed for remote northern oceanic regions.
a b s t r a c tThe response to hemispherical and regional aircraft NO x emissions is explored by using two climate metrics: radiative forcing (RF) and Global Warming Potential (GWP). The global chemistry transport model, MOZART-3 CTM, is applied in this study for a series of incremental aircraft NO x emission integrations to different regions. It was found that the sensitivity of chemical responses per unit emission rate from regional aircraft NO x emissions varies with size of aircraft NO x emission rate and that climate metric values decrease with increasing aircraft NO x emission rates, except for Southeast Asia. Previous work has recognized that aircraft NO x GWPs may vary regionally. However, the way in which these regional GWPs are calculated are critical. Previous studies have added a fixed amount of NO x to different regions. This approach can heavily bias the results of a regional GWP because of the well-established sensitivity of O 3 production to background NO x whereby the Ozone Production Efficiency (OPE) is greater at small background NO x . Thus, even a small addition of NO x in a clean-air area can produce a large O 3 response. Using this 'fixed addition' method of 0.035 Tg(N) yr À1 , results in the greatest effect observed for North Atlantic and Brazil,~10.0 mW m À2 /Tg(N) yr À1 . An alternative 'proportional approach' is also taken that preserves the subtle balance of local NO x eO 3 eCH 4 systems with the existing emission patterns of aircraft and background NO x , whereby a proportional amount of aircraft NO x , 5% (N) yr À1 , is added to each region in order to determine the response. This results in the greatest effect observed for North Pacific that with its net NO x RF of 23.7 mW m À2 /Tg(N) yr À1 is in contrast with the 'fixed addition' method. For determining regional NO x GWPs, it is argued that the 'proportional' approach gives more representative results. However, a constraint of both approaches is that the regional GWP determined is dependent on the relative global emission pattern, so if that changes in the future, the regional NO x GWP will change.