Resonance electronic Raman effect in DyAlG

Wadsack, R. L.; Chang, Richard K.

doi:10.1016/0038-1098(72)90344-4

Cited by 16 publications

(2 citation statements)

References 16 publications

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“…The electronic Raman transitions of rare earth ions and crystal field effects have been reviewed (148), and the effect has been used in spectroscopic studies of neodymium alumínate (149) and cobalt germanate (150). Electronic stimulated Raman scattering has been demonstrated in atomic thallium vapor (151), and a resonance electronic Raman effect has been observed in dysprosium aluminum garnet (152).…”

Section: Stimulated Electronic Hyper- Andmentioning

confidence: 99%

Raman spectrometry

Grossman¹

1974

Anal. Chem.

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This Review covers selected portions of the literature appearing between late 1971 and late 1973. Activity in the field has continued at a high level since the previous review in this series (1), and it seems neither possible nor desirable to give a comprehensive coverage of the published literature. The emphasis here will be on the chemical applications of Raman spectrometry, especially in the areas of analysis and instrumentation, as being most like-ly to be of interest to the readers of this journal. Where possible, reviews and other secondary sources which give more detailed coverage of smaller areas will be referenced.Several new books have appeared during the time covered by the review (2-7), evidence of the need for consolidation and ordering in a rapidly growing field. A critical compilation of vibrational frequencies of 55 polyatomic molecules has been published (8). Inorganic vibrational

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Section: Stimulated Electronic Hyper- Andmentioning

confidence: 99%

Raman spectrometry

Grossman¹

1974

Anal. Chem.

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“…Since x< 3 )R is roughly proportional to the spontaneous Raman cross section, one has(2.25) The resonant susceptibility for electronic CARS, •x<!~ is often so s~all that it is obscured by x(3)NR which can be orders of magnitude larger. This is especially true for dilute rare earth crystals, since x<3JR is proportional to the number density of rare earth ions in the crystal.Experiments[77][78][79][80][81][82][83] have shown that ERS cross sections in rare earth crystals can be resonantly enhanced when the frequency of the exciting laser is near the energy of an electronic level of the rare earth ion. These studies included inter-and intra-configurational resonances.…”

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confidence: 99%

Nonlinear Optical Spectroscopy of Ce<sup>3+</sup> Ions in Insulating Crystals

Piehler

1990

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Coherent anti-Stokes Raman spe~troscopy (CARS) involving electronic states of rare earth ions in insulating crystals has shown only limited success, unlike CARS involving vibrational transitions. The major problem is that x< 3 >R, the contribution to the third order susceptibility from the electronic states of the rare earth ions, is often obscured by x< 3 >NR, the contribution from the b~lk crystal which can be orders of magnitude larger. 3.3 Selection Rules 3.4 Experimental Details 3.5 Results and Discussion 3.5.1 2Fsn (r6) ~ 5d (r7)3.5.2 2Fsn (r6) ~ 5d

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1.3.5.2 IR, UV and Raman spectra, and index of refraction

Gunßer¹,

Wolfmeier²,

Fleischhauer³

Landolt-Börnstein - Group III Condensed Matter

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Resonance electronic Raman effect in DyAlG

Cited by 16 publications

References 16 publications

Raman spectrometry

Raman spectrometry

Nonlinear Optical Spectroscopy of Ce<sup>3+</sup> Ions in Insulating Crystals

1.3.5.2 IR, UV and Raman spectra, and index of refraction

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