Recent Developments in Enantioselective Domino Reactions. Part A: Noble Metal Catalysts

Abstract

This review updates the field of enantioselective domino reactions promoted by chiral catalysts derived from noble metals, including palladium, silver, rhodium, ruthenium, iridium and gold, published since the beginning of 2019. It illustrates how much a diversity of these catalysts allow unprecedented asymmetric domino reactions of many types to be achieved with excellent enantioselectivity, giving a direct access to a wide variety of complex chiral molecules. Enantioselective Ruthenium-Catalyzed Domino Reactions 6.Enantioselective Iridium-Catalyzed Domino Reactions 7.Enantioselective Gold-Catalyzed Domino Reactions 8. Conclusions List of abbreviations Part A

Recent Developments in Enantioselective Scandium-Catalyzed Transformations

“…A wide number of asymmetric domino reactions have been successfully catalyzed by many types of chiral metal complexes, allowing the synthesis of very complex molecules [30][31][32][33][34][35][36][37][38][39][40][41][42][43][44][45]. In the last few years, different types of chiral ligands, including N,N ′ -dioxides, pyridine-2,6-bisoxazolines, bipyridines, phosphine oxides, and phosphoric acids, have been chelated to scandium to promote a range of unprecedented highly efficient domino reactions.…”

A New Impregnated Adsorbent for Noble Metal Ion Sorption

“…Owing to their unique properties, they are used for the production of automotive exhaust gas converters [ 1 ]. Enantioselective domino reactions are promoted by the chiral catalysts derived from noble metals [ 2 ]. Precious metals are also a capital investment.…”

Asymmetric cascades of the π-allyl complex: a journey from transition-metal catalysis to metallaphotocatalysis

“…Catalytic enantioselective cascades have been one of the preferred strategies for the construction of asymmetric C-C and C-X centres. [1][2][3][4][5][6][7][8][9][10][11][12] These processes are so economical and viable that they have found abundant use among the synthetic community and have been used for the synthesis of valuable bio-active natural products, pharmacophores, and synthetically useful intermediates. In this domain, the enantioselectivity could be achieved through organocatalysis or transition-metal catalysis, where a transition metal complex is used along with a chiral ligand.…”