Reactions of the triosmium complex Os3(CO)10(μ-Br)(CHCHPh) with benzyl isonitrile and triphenylphosphine. Crystal structure and solut fluxionality of the ethenyl derivatives

Chuang, Shiow‐Huey; Chi, Yun; Liao, Fen‐Ling; Wang, Sue‐Lein; Peng, Shie‐Ming; Lee, Gene‐Hsiang; Wu, Jyh‐Lin; Horng, Keh-Ming

doi:10.1016/0022-328x(91)83027-2

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Cited by 6 publications

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Chemistry of heterometallic phenyl imido and phosphinidene clusters

et al. 1992

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Trirutheniurn imido cluster Ru3(CO)lo(p3-NPh) (I) reacts with tungsten hydride LW(CO)3H to afford heterometallic imido clusters LWRu2(CO)8(#-H) (p~-NPh), L = Cp, (IIa); L = Cp*, (IIh), whereas the respective phosphinidene complexes LWRu2(CO)8(#-H)(#3-PPh), L=Cp, (IXa); L=Cp*, (IXb), were generated via reaction of Ru3(CO)Io(#-H)(#-PPh2) with CpW(CO)3H and with Cp*W(CO)3H followed by thermolysis in the presence of carbon monoxide. Their molecular structure, solution dynamics, and the subsequent reaction with hexafluoro-2-butyne are presented.

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