Chemistry of heterometallic phenyl imido and phosphinidene clusters

Chi, Yun; Lin, Ren-Chiun; Peng, Shie‐Ming; Lee, Gene‐Hsiang

doi:10.1007/bf01028550

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Cited by 4 publications

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Synthesis of Thiolato Heterometalllc Clusters from the Reaction of Os₃(CO)₉(NCMe)(μ‐H)(μ‐SMe) with CpW(CO)₃H

Tsay

Chi

et al. 1994

J Chinese Chemical Soc

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Decarbonylationof triosmiummethylthiolato cluster OS3(CO)IO(J.l-H)(J.l-SMe) with Me3NO in acetonitrile solution gave cluster OS3(COMNCMe){J.l-H){J.l-SMe) (1), in which one axial CO on the non-bridged Os atom is replaced by an acetonitrile ligand. Crystal data for Z: space group P bca, a = 14.491 (I), b ;:;16.107(5), c =16.639(5) A, Z =8; R F =0.037, R, =0.033. Treatment of 2 with CpW(CO)3H in refluxing THF solution yielded two cluster compounds with formula CpWOs3(CO)1l(Il-HMIl3-SMe) (2) and CpWOsiCO)lJijJ.-HMfl-SMe) (3) as the principle products. The first possesses a spiked-triangular geometty with a triply bridging thiolato ligand and the second adopts a burterfly metal core arrangement with an edge-bridging thiolato grouping. The structure of 2 was characterized by single-crystal X-ray diffraction.Crystal data: space group P T, a = 8.865 (5), b;:; 8.959(3), c = 16.688(4) A, (X = 103.49(2),~= 93.58(3), ' Y = 113.03(4)", Z == 2, R F = 0.034, R", = 0.035.

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Synthesis of Thiolato Heterometalllc Clusters from the Reaction of Os₃(CO)₉(NCMe)(μ‐H)(μ‐SMe) with CpW(CO)₃H

Tsay

Chi

et al. 1994

J Chinese Chemical Soc

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Synthesis and properties of mixed-metal phosphido and phosphinidene clusters derived from reaction between Ru3(CO)10(μ-H)(μ-PPh2) and Cp★ Mo(CO)3H

Wang

Chi

Peng

et al. 1994

Journal of Organometallic Chemistry

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Heteronuclear Clusters Containing C1, C2, C3, …, C Acyclic Hydrocarbyl Ligands

Chi

Hwang

1995

Comprehensive Organometallic Chemistry II

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Chemistry of heterometallic phenyl imido and phosphinidene clusters

Cited by 4 publications

References 48 publications

Synthesis of Thiolato Heterometalllc Clusters from the Reaction of Os₃(CO)₉(NCMe)(μ‐H)(μ‐SMe) with CpW(CO)₃H

Synthesis of Thiolato Heterometalllc Clusters from the Reaction of Os₃(CO)₉(NCMe)(μ‐H)(μ‐SMe) with CpW(CO)₃H

Synthesis and properties of mixed-metal phosphido and phosphinidene clusters derived from reaction between Ru3(CO)10(μ-H)(μ-PPh2) and Cp★ Mo(CO)3H

Heteronuclear Clusters Containing C1, C2, C3, …, C Acyclic Hydrocarbyl Ligands

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Chemistry of heterometallic phenyl imido and phosphinidene clusters

Cited by 4 publications

References 48 publications

Synthesis of Thiolato Heterometalllc Clusters from the Reaction of Os3(CO)9(NCMe)(μ‐H)(μ‐SMe) with CpW(CO)3H

Synthesis of Thiolato Heterometalllc Clusters from the Reaction of Os3(CO)9(NCMe)(μ‐H)(μ‐SMe) with CpW(CO)3H

Synthesis and properties of mixed-metal phosphido and phosphinidene clusters derived from reaction between Ru3(CO)10(μ-H)(μ-PPh2) and Cp★ Mo(CO)3H

Heteronuclear Clusters Containing C1, C2, C3, …, C Acyclic Hydrocarbyl Ligands

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Synthesis of Thiolato Heterometalllc Clusters from the Reaction of Os₃(CO)₉(NCMe)(μ‐H)(μ‐SMe) with CpW(CO)₃H

Synthesis of Thiolato Heterometalllc Clusters from the Reaction of Os₃(CO)₉(NCMe)(μ‐H)(μ‐SMe) with CpW(CO)₃H