Reaction sintering of titanium carbide and titanium silicide prepared by high-energy milling

Low-temperature fabrication of high purity Ti3SiC2

“…1 may be an indication that SHS reactions [10,11] occurred during the milling process, and excess Al addition suppressed such reactions.…”

“…Jingfeng Li et al synthesized Ti 3 SiC 2 with the purity of 95.8 vol% by mechanical alloying of the 3Ti/Si/2C powder mixture for 10 h, and subsequent vacuum heat-treating at 1000 • C for 1 h [10]. Orther fabricated single-phase Ti 3 SiC 2 by sintering using a 1 h ball-milled powder mixture consisting of 3Ti/(1 + x) Si/2C(0.1,0.2,0.3) at 1350 • C for 2 h [11].…”

Processing of Al matrix composites reinforced with Al–Ni compounds and Al2O3 by reactive milling and reactive sintering

“…However, for some systems, particularly non-SHS reactions, complete conversion to the desired product phases cannot be achieved only during milling. The final composite can be formed during subsequent sintering through a reactive sintering process [12].…”

Synthesis of Ti3SiC2 in air using mechanically activated 3Ti/Si/2C powder

“…A self-propagating reaction could be triggered by mechanical alloying of 3Ti/Si/2C with a large negative heat formatted [2]. Ti 3 SiC 2 was also successfully synthesized by mechanical alloying of elemental mixtures of Ti, Si and C [2][3][4].…”

“…Ti 3 SiC 2 was also successfully synthesized by mechanical alloying of elemental mixtures of Ti, Si and C [2][3][4]. Takeshi Tsuchida [5] developed a technique combing mechanical activation and SHS by milling.…”