1986
DOI: 10.1088/0022-3719/19/10/004
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Raman investigation of the InP lattice dynamics

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Cited by 57 publications
(31 citation statements)
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“…The other two peaks, at 306.4 and 309.4 cm Ϫ1 , do not show any dependence on carrier density. The existence of an additional peak close to the TO mode, which we have also observed in undoped InP, was previously assigned to a second-order overtone of the longitudinal acoustic modes at zone edge 32 lying very close to the TO frequency. Given that a precise value of the TO energy is necessary as an input of the LOPCM line-shape model, it is important to unambiguously identify the TO peak in the Raman spectra.…”
supporting
confidence: 75%
“…The other two peaks, at 306.4 and 309.4 cm Ϫ1 , do not show any dependence on carrier density. The existence of an additional peak close to the TO mode, which we have also observed in undoped InP, was previously assigned to a second-order overtone of the longitudinal acoustic modes at zone edge 32 lying very close to the TO frequency. Given that a precise value of the TO energy is necessary as an input of the LOPCM line-shape model, it is important to unambiguously identify the TO peak in the Raman spectra.…”
supporting
confidence: 75%
“…Given this close agreement and the computational cost involved, we will neglect spin-orbit coupling for the WZ InP phonon-dispersion calculations. Available experimental phonon-dispersion data [12,35] for ZB InP are also shown in Fig. 1(a).…”
Section: Phonon Dispersionsmentioning
confidence: 99%
“…While an early work [10] using an overlap valence shell model was able to fit the measured ZB InP phonon dispersion [10][11][12], this empirical approach required ten fitting parameters and did not provide significant physical insight. Ab initio lattice-dynamical calculations for ZB InP [13][14][15] using density-functional perturbation theory (DFPT) [16] are in excellent agreement for the measured acoustic branches but overestimate the optical frequencies.…”
Section: Introductionmentioning
confidence: 99%
“…Here the surface phonon above the LO mode and the asymmetric shoulder of TO phonon are resolved as separate peaks. The structure above the TO mode is not surface related, it might either be attributed to a secondorder bulk phonon process, the 2LA(K,W), or a disorder-activated TO mode [32]. The peaks of the three localized surface phonons at 258, 274 and 355 cm À1 have slightly larger full widths at half maximum (2.7-3 cm À1 ) than the TO (1.8 cm À1 ) and the LO (2.4 cm À1 ) bulk phonons.…”
Section: Raman Resultsmentioning
confidence: 98%