Raman spectroscopy measurements have been performed on GaAs:Be samples with high crystalline quality and exceptional heavy doping level ranging from 1019 to 1.4×1021 cm−3. The recorded spectra show a structure we assigned to a coupled LO phonon-damped plasmon mode. A theoretical expression for the Raman scattering rate by this mode has been derived from a dielectric model and compared to the experimental data. Using a fitting procedure the doping level of the samples has been estimated in agreement with Hall measurements. Moreover, the study of the Raman intensity evolution of both unscreened-LO and coupled phonon-plasmon structures, provided a convenient and rapid method to determine the activated carrier density in p-doped polar semiconductors. Disorder effects due to the dopant impurities have been also observed and analyzed using a spatial correlation model description.
First- and second-order Raman scattering by Zn-implanted InP is investigated in order to determine critical fluences needed for a complete disturbance of the lattice and recovery temperature during thermal annealing. Disorder-activated first-order acoustical scattering and second-order optical scattering are shown to be highly sensitive probes.
We have found that the local density of state fluctuations (LDOSF) in a disordered metal, detected using an impurity in the barrier as a spectrometer, undergo enhanced (with respect to Shubnikov-de Haas and de Haas-van Alphen effects) oscillations in strong magnetic fields, omega(c)tau>/=1. We attribute this to the dominant role of the states near the bottom of Landau bands which give the major contribution to the LDOSF and are most strongly affected by disorder. We also demonstrate that in intermediate fields the LDOSF increase with field B in accordance with the results obtained in the diffusion approximation.
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