Activity concentrations of natural radionuclides in some river waters in southwestern Nigeria were measured using high-purity germanium (HPGe) detector. The activity concentrations ranged from 0.12 to 2.31, 0.17 to 2.85, and 7.86 to 65.51 Bq l-1 for 226Ra, 228Ra, and 40K respectively. The calculated mean of the total annual effective dose were 9.86, 2.46, 1.71, 2.43, 5.74 and 0.99 mSv y-1 for age groups ≤1y, 1-2y, 2-7y, 7-12y, 12-17y, and >17y respectively. Estimated cancer mortality and morbidity risks ranged from 0.04x10-3 to 0.77x10-3 with a mean of 0.42x10-3 and 0.04x10-3 to 0.80x10-3 with a mean of 0.44x10-3 respectively for 226R while they ranged from 0.11x10-3 to 1.89x10-3 with a mean of 0.96x10-3 and 0.16x10-3 to 2.66x10-3 with a mean of 1.38x10-3 respectively for 228Ra. The lifetime average daily dose (LADD) of 226Ra and 228Ra ranged from 9.39x10-14 µg kg-1 d-1 to 181.01x10-14 µg kg-1 d-1 with a mean of 100.06x10-14 µg kg-1 d-1 and 4.82x10-16 µg kg-1 d-1 to 80.70x10-16 µg kg-1 d-1 with a mean of 40.90x10-16 µg kg-1 d-1 respectively.. Radiological hazard indicator of radium is of concern in these drinking river water samples.