Pulsed discharge in a hollow cathode with the detection of ions in a time-of-flight mass spectrometer: Analytical capabilities in the analysis of solid samples

Ганеев, А. А.; Kuzmenkov, M. A.; Lyubimtsev, V. A.; Потапов, С.; Drobyshev, A. I.; Potemin, S. S.; Voronov, M.

doi:10.1134/s1061934807050097

Cited by 23 publications

(23 citation statements)

References 26 publications

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“…This mass spectrometer uses HC PGD as the source of ions. Several types of hollow cathodes may be installed in the system: a thin-walled monolithic hollow cathode [21] for dry residues analysis, monolithic thick-walled and combined cathodes for solid sample analysis [24]. In this article only the thin-walled monolithic HC and the combined one are considered because typical parameters, and therefore the main processes, for the thick-walled HC and the combined one are the same.…”

Section: Model Assumptionsmentioning

confidence: 99%

“…The discharge geometry in the model is the same as in commercial time-of-flight mass spectrometer "Lumas-30" [24,45], see Fig. 1.…”

Section: Model Assumptionsmentioning

confidence: 99%

“…Application of HC in the pulsed mode leads to a combination of the advantages: higher sensitivity, possibility for direct analysis of conducting, semi-conducting and insulating materials [3,24], high rate of excitation and ionization of the sample atoms. Moreover HC PGD can be used for depth profile analysis [3].…”

Section: Introductionmentioning

confidence: 99%

“…In the last decade HC PGD has been investigated as a source of ions for mass spectrometry [15,16,[19][20][21][22][23][24]. Application of HC in the pulsed mode leads to a combination of the advantages: higher sensitivity, possibility for direct analysis of conducting, semi-conducting and insulating materials [3,24], high rate of excitation and ionization of the sample atoms.…”

Section: Introductionmentioning

confidence: 99%

“…In this work we present a model of a microsecond PGD and its afterglow in HC, and the application of the model for the optimization of a developing commercial Time-of-Flight mass spectrometer "Lumas-30" [22][23][24]45] with HC PGD as an ion source. In the hybrid model [29][30][31][32][33][34][35][36][37][38][39][40][41][42][43][44] different submodels are used for simulation of different particles.…”

Section: Introductionmentioning

confidence: 99%

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Model of microsecond pulsed glow discharge in hollow cathode for mass spectrometry

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Ганеев

2009

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Section: Model Assumptionsmentioning

confidence: 99%

“…The discharge geometry in the model is the same as in commercial time-of-flight mass spectrometer "Lumas-30" [24,45], see Fig. 1.…”

Section: Model Assumptionsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

Model of microsecond pulsed glow discharge in hollow cathode for mass spectrometry

Voronov¹,

Ганеев

2009

Spectrochimica Acta Part B: Atomic Spectroscopy

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Current literature in mass spectrometry

2007

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of mass spectrometry for the structural characterization of recombinant protein pharmaceuticals. Mass Spectrom Rev 2007; 26: 370. Bharti A, Ma PC, Salgia R. Biomarker discovery in lung cancer -Promises and challenges of clinical proteomics. Mass Spectrom Rev 2007; 26: 451. Drabik A, Bierczynska-Krzysik A, Bodzon-Kulakowska A, Suder P, Kotlinska J, Silberring J. Proteomics in neurosciences. Mass Spectrom Rev 2007; 26: 432. Greis KD. Mass spectrometry for enzyme assays and inhibitor screening: An emerging application in pharmaceutical research. Mass Spectrom Rev 2007; 26: 324. Prakash C, Shaffer CL, Nedderman A. Analytical strategies for identifying drug metabolites. Mass Spectrom Rev 2007; 26: 340. Tamvakopoulos C. Mass spectrometry for the quantification of bioactive peptides in biological fluids. Mass Spectrom Rev 2007; 26: 389. Zhang XW, Wei D, Yap Y, Li L, Guo SY, Chen F. Mass spectrometry-based "omics" technologies in cancer diagnostics. Mass Spectrom Rev 2007; 26: 403. INSTRUMENTAL TECHNIQUES & METHODSAdamov A, Viidanoja J, Karpanoja E, Paakkanen H, Ketola RA, Kostianinen R, Sysoev A, Kotiaho T. Interfacing an aspiration ion mobility spectrometer to a triple quadrupole mass spectrometer. Rev Sci Instrum 2007; 78: 44101.Asfandiarov NL, Nafikova EP, Pshenichnyuk SA. Interpreting electron transmission spectroscopy and negative ion mass spectrometry data using a spherical potential well model. J Exp Theor Phys 2007; 104: 357. Bader S, Urfer W, Baumbach JI. Reduction of ion mobility spectrometry data by clustering characteristic peak structures. J Chemometr 2006; 20: 128. Blashenkov NM, Lavrent'ev GY. Surface-ionization field mass-spectrometry studies of nonequilibrium surface ionization. Phys Usp 2007; 50: 53. Breitenfeldt M, Ziegler F, Herlert A, Marx G, Schweikhard L. Simultaneous monitoring of the radial modes of the ion motion and their manipulation in Penning traps by FT-ICR mass spectrometry. Int J Mass Spectrom 2007; 263: 94. Chen H, Wortmann A, Zenobi R. Special feature: Tutorial -Neutral desorption sampling coupled to extractive electrospray ionization mass spectrometry for rapid differentiation of biosamples by metabolomic fingerprinting. J Mass Spectrom 2007; 42: 1123. Creese AJ, Cooper HJ. Liquid chromatography electron capture dissociation tandem mass spectrometry (LC-ECD-MS/MS) versus liquid chromatography collision-induced dissociation tandem mass spectrometry (LC-CID-MS/MS) for the identification of proteins. J Am Soc Mass Spectrom 2007; 18: 891. Delcorte A, Yunus S, Wehbe N, Nieuwjaer N, Poleunis C, Felten A, Houssiau L, Pireaux JJ, Bertrand P. Metal-assisted secondary ion mass spectrometry using atomic (Ga + , In + ) and fullerene projectiles. Anal Chem 2007; 79: 3673. Falkner JA, Kachman M, Veine DM, Walker A, Strahler JR, Andrews PC. Validated MALDI-TOF/TOF mass spectra for protein standards. J Am Soc Mass Spectrom 2007; 18: 850. Ganeev AA, Kuz'menkov MA, Lyubimtsev VA, Potapov SV, Drobyshev AI, Potemin SS, Voronov MV. Pulsed discharge in a hollow cathode with the detection of ions in a time-...

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Detection of explosives using a hollow cathode discharge ion source

Habib

Chen

Usmanov

et al. 2015

Rapid Commun. Mass Spectrom.

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Because the major NOx(-) ions (x = 2, 3) produced in the plasma act as reagent ions in ion-molecule reactions of explosives, air is best suited as a carrier gas for the detection of explosives. It is proposed that the NOx(-) (x = 2, 3) and O3 contributed to the formation of [TNT-H](-) and [TNT-NO](-) ions, via the reactions NOx(-) + TNT → [TNT-H](-) + HNOx and [TNT](-) + O3 → [TNT-NO](-) + NO2 + O2.

show abstract

Pulsed discharge in a hollow cathode with the detection of ions in a time-of-flight mass spectrometer: Analytical capabilities in the analysis of solid samples

Cited by 23 publications

References 26 publications

Model of microsecond pulsed glow discharge in hollow cathode for mass spectrometry

Model of microsecond pulsed glow discharge in hollow cathode for mass spectrometry

Current literature in mass spectrometry

Detection of explosives using a hollow cathode discharge ion source

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