“…On the other hand, SnS 2 NPs show n-type polarity. 33,[51][52][53][54][55][56] The electron affinity and bandgap of SnS 2 NPs are 4.2 eV and 2.7-3.3 eV, 33,53,54 while the electron affinity and bandgap of SnS are 4.0 eV and 1.2 eV. Thus, for NP-NS hybrid films, due to the carrier concentration gradient, the hole carriers from p-SnS NS diffuse into n-SnS 2 NPs, and electrons diffuse from n-SnS 2 NPs into p-SnS NSs, forming space charge regions at the interfaces and reducing the concentration of free carriers in SnS NSs due to charge carrier recombination.…”