Preparation, Structural Characterization, and Thermal Analysis of Nitrogen‐rich Energetic Ionic Salts based on 4‐Amino‐3‐hydrazino‐5‐mercapto‐1, 2,4‐triazole

Abstract

Abstract. Two heterocyclic-based energetic ionic salts were synthesized from 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (1), which was used as proton bases reacting with nitric or perchloric acid. They were characterized by elemental analysis, IR spectroscopy, and singlecrystal X-ray diffraction. In addition, their combustion heats were measured by oxygen bomb calorimetry and their heats of formation were predicted based on the combustion heats data. The non-isothermal ki-