As a key research objective for environmentally friendly energetic materials, energetic salts without heavy metal have received wide attention. The energetic salts DAG·PA·H 2 O (1) and DAG·TNR·H 2 O (2) were synthesized by using diamino-glyoxine (DAG) and picric acid (PA) or 2,4,6-trinitro-resorcinol (TNR) as raw materials, and their structures were characterized by elemental analysis, FT-IR, 1 H NMR, and 13 C NMR spectroscopy. Single crystals of the title salts were cultured and their structures were determined by Xray single-crystal diffraction. Both salts belong to the triclinic space group P1 with density values of 1.764 and 1.751 g·cm -3 , respectively.