Preparation of Heteropoly Acid/Porous Hybrid Materials and Investigation of their Catalytic Behavior in the Synthesis of Perimidine

Zendehdel, Mojgan; Mobinikhaledi, Akbar; Alikhani, H.; Jafari, N.

doi:10.1002/jccs.201000095

Cited by 15 publications

(7 citation statements)

References 51 publications

(37 reference statements)

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“…In 2010, Zendehdel et al [70] synthesized perimidines using a series of hybrid heteropolyacids (HPA) by refluxing 1,8-naphthalenediamine (NDA) and aromatic aldehydes in ethanol for 5 h at 80 °C. The order of the catalytic efficiency is as follows: HPA/NaY > HPA/NaY/MCM-41 > NaY > HPA > MCM-41.…”

Section: Acid-catalyzed Synthesismentioning

confidence: 99%

Recent Advances in the Synthesis of Perimidines and their Applications

Sahiba¹,

Agarwal²

2020

Top Curr Chem (Z)

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Perimidines are versatile scaffolds and a fascinating class of N-heterocycles that have evolved significantly in recent years due to their immense applications in life sciences, medical sciences, and industrial chemistry. Their ability of molecular interaction with different proteins, complex formation with metals, and distinct behavior in various ranges of light makes them more appealing and challenging for future scientists. Various novel technologies have been developed for the selective synthesis of perimidines and their conjugated derivatives. These methods extend to the preparation of different bioactive and industrially applicable molecules. This review aims to present the most recent advancements in perimidine synthesis under varied conditions like MW radiation, ultrasound, and grinding using different catalysts such as ionic liquids, acid, metal, and nanocatalyst and also under green environments like catalyst and solvent-free synthesis. The applications of perimidine derivatives in drug discovery, polymer chemistry, photo sensors, dye industries, and catalytic activity in organic synthesis are discussed in this survey. This article is expected to be a systematic, authoritative, and critical review on the chemistry of perimidines that compiles most of the state-of-art innovation in this area.

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Section: Acid-catalyzed Synthesismentioning

confidence: 99%

Recent Advances in the Synthesis of Perimidines and their Applications

Sahiba¹,

Agarwal²

2020

Top Curr Chem (Z)

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“…Zendehdel et al reported the synthesis of PW 12 /NaY and PW 12 /NaY/MCM-41 composites by synthesis of the zeolite in the presence of the polyoxometalate [33]. HPW 12 (10 g) was mixed with 16.13 g of sodium silicate and 6 mL of the initiator (with the composition 16 Na 2 O:Al 2 O 3 :15 SiO 2 :320 H 2 O aged at 32˝C for 32 h).…”

Section: Synthesis Of the Zeolite Around The Polyoxometalatementioning

confidence: 99%

Synthesis, Characterization and Applications in Catalysis of Polyoxometalate/Zeolite Composites

Lefèbvre

2016

Inorganics

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An overview of the synthesis, characterization and catalytic applications of polyoxometalates/zeolites composites is given. The solids obtained by direct synthesis of the polyoxometalate in the presence of the zeolite are first described with their applications in catalysis. Those obtained by a direct mixing of the two components are then reviewed. In all cases, special care is taken in the localization of the polyoxometalate, inside the zeolite crystal, in mesopores or at the external surface of the crystals, as deduced from the characterization methods.

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“…Reaction of 1,8‐diaminonaphthalene with aldehydes and ketones results in the formation of 2,3‐dihydro‐1 H ‐perimidines which can be converted to perimidines by dehydrogenation . The existing reports for its synthesis involve the use of various catalysts like NaY‐Zeolite, Cu(NO 3 ) 2 .6H 2 O, Zn(OAc) 2 .2H 2 O,8b HPA/NaY, I 2 , FePO 4 , nano‐CuY zeolite, Fe 3 O 4 @β‐CD‐ZrO etc. in organic solvents yielding products in moderate to good yields …”

Section: Introductionmentioning

confidence: 99%