Practical Challenges Associated with Catalyst Development for the Commercialization of Li-air Batteries

Abstract

Li-air cell is an exotic type of energy storage and conversion device considered to be half battery and half fuel cell. Its successful commercialization highly depends on the timely development of key components. Among these key components, the catalyst (i.e., the core portion of the air electrode) is of critical importance and of the upmost priority. Indeed, it is expected that these catalysts will have a direct and dramatic impact on the Li-air cell's performance by reducing overpotentials, as well as by enhancing the overall capacity and cycle life of Li-air cells. Unfortunately, the technological advancement related to catalysts is sluggish at present. Based on the insights gained from this review, this sluggishness is due to challenges in both the commercialization of the catalyst, and the fundamental studies pertaining to its development. Challenges in the commercialization of the catalyst can be summarized as 1) the identification of superior materials for Li-air cell catalysts, 2) the development of fundamental, material-based assessments for potential catalyst materials, 3) the achievement of a reduction in both cost and time concerning the design of the Li-air cell catalysts. As for the challenges concerning the fundamental studies of Li-air cell catalysts, they are 1) the development of experimental techniques for determining both the nano and micro structure of catalysts, 2) the attainment of both repeatable and verifiable experimental characteristics of catalyst degradation, 3) the development of the predictive capability pertaining to the performance of the catalyst using fundamental material properties. Therefore, under the current circumstances, it is going to be an extremely daunting task to develop appropriate catalysts for the commercialization of Li-air batteries; at least within the foreseeable future. Regardless, nano materials are expected to play a crucial role in this field.

Continuous Hydrothermal Synthesis of Inorganic Nanoparticles: Applications and Future Directions

“…Its successful commercialization will depend on the timely development of key components (including nanocatalysts, which will be a key part of the air electrode). 593 Within the next 30 years or longer, cathodes cocatalyst components for Li-air batteries may also be required to be nanosized, and CHFS will be an ideal way to make such materials. Looking to the future, there are exciting possibilities to develop multivalent cathodes (e.g., Al or Mg−ion batteries) such as those based around spinel structures 594 possessing large pores.…”