Single-phase Pb(Fe 2/3 W 1/3) O 3 (PFW) multiferroic ceramics doped with magnetic ions were fabricated using a modified B-site precursor method. Dielectric response was investigated over a wide range of temperature and frequency. Doping did not modify the characteristic temperatures (T C , T N ) and the order at ferroelectric phase transition, keeping the relaxor properties. However, the leakage current and resistivity of PFW have been improved with the substitutions: 1 mol% MnO 2 addition caused a significant increase in the electric resistivity of PFW ceramics, around 7 orders of magnitude.