2007
DOI: 10.1107/s1600536807036598
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Poly[sodium [μ4-2-hydroxyphosphonoacetato(3−)]iron(II)]

Abstract: CommentMetal phosphonates with rich composition and structural diversity have attracted considerable attention during the past few years due to their potential applications in catalysis (Clearfield, 1996), ion exchange (Alberti et al., 1999), proton

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Cited by 3 publications
(4 citation statements)
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References 5 publications
(10 reference statements)
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“…The structure of NaFe[O 3 PCH(OH)CO 2 ] 21 formed by the phosphoryl organic and Fe 2+ ions is shown in 1b, the calculated XRD diffraction peaks of the purple line are highly consistent with the reported PXRD diffraction peaks of the black line 21,23 . The calculated three strongest diffraction peaks at 19.95°, 30.42° and 31.97° correspond to the crystal planes (021), (222), and (213), respectively, while the experimental PXRD showed these peaks shifted to 19.98°, 30.19°, and 31.62°.…”
Section: Resultssupporting
confidence: 70%
“…The structure of NaFe[O 3 PCH(OH)CO 2 ] 21 formed by the phosphoryl organic and Fe 2+ ions is shown in 1b, the calculated XRD diffraction peaks of the purple line are highly consistent with the reported PXRD diffraction peaks of the black line 21,23 . The calculated three strongest diffraction peaks at 19.95°, 30.42° and 31.97° correspond to the crystal planes (021), (222), and (213), respectively, while the experimental PXRD showed these peaks shifted to 19.98°, 30.19°, and 31.62°.…”
Section: Resultssupporting
confidence: 70%
“…Anionic frameworks with fully deprotonated trianionic HPAA 3− have been reported with divalent metal ions. ,, In these structures an extra organic or inorganic cation is also incorporated for charge balance. The inclusion of Na + as charge-compensating cation into the anionic framework has led to a series of isomorphous orthorhombic 3D compounds, NaM{O 3 PCH(OH)CO 2 } (M = Mn, Fe, Co, Zn), MNa-L-0-0-3D , obtained by hydrothermal syntheses. The resulting frameworks incorporate the alkali metal ions as a compensation for the increase in the M/P molar ratio and also for the increased pH above 4.0 (for instance by the presence of an acetate buffer).…”
Section: Resultsmentioning
confidence: 99%
“…Yet, rational design of the synthesis of metal phosphonates, M n + -HPAA, is not an easy task because of a large number of experimental factors that must be precisely controlled. One-dimensional (1D), two-dimensional (2D), , and three-dimensional (3D) ,,, materials based on the HPAA ligand have been reported. Generally, reactions of hydrated metal salts and HPAA at low pH (ca.…”
Section: Introductionmentioning
confidence: 99%
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