A version of Kirillov's orbit method states that the primitive spectrum of a generic quantisation A of a Poisson algebra Z should correspond bijectively to the symplectic leaves of Spec(Z). In this article, we consider a Poisson order A over a complex affine Poisson algebra Z. We stratify the primitive spectrum Prim(A) into symplectic cores, which should be thought of as families of non‐commutative symplectic leaves. We then introduce a category A-P-Mod of A‐modules adapted to the Poisson structure on Z, and we show that when Spec(Z) is smooth with locally closed symplectic leaves, there is a natural homeomorphism from the spectrum of annihilators of simple objects in A-P-Mod to the set of symplectic cores in Prim(A) with its quotient topology. Several applications are given to Poisson representation theory. Our main tool is the Poisson enveloping algebra Ae of a Poisson order A, which captures the Poisson representation theory of A. For Z regular and affine, we prove a Poincarée–Birkhoff–Witt (PBW) theorem for Ae and use this to characterise the annihilators of simple Poisson modules: they coincide with the Poisson weakly locally closed, the Poisson primitive and the Poisson rational ideals. We view this as a generalised weak Poisson Dixmier–Mœglin equivalence.