2013
DOI: 10.1063/1.4798331
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Plasmon dispersion in quasi-freestanding graphene on Ni(111)

Abstract: The electronic properties of graphene formed on Ni(111) by chemical vapor deposition and intercalated with Cs atoms have been studied by angle-resolved electron-energy-loss spectroscopy. The dispersion curve of π plasmon, in comparison with the analogous dispersion curve obtained in the absence of intercalated Cs, shows that alkali metal atoms make graphene to be quasi-free, with a much lowered charge transfer, and with the recovery of the π band linearity at Dirac points.

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Cited by 31 publications
(24 citation statements)
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“…In the case of graphene on metals, the ability of intercalated chemical species to decouple graphene from the Ni(111), recovering the Dirac fermion character of its collective excitations (phonon [9,[14][15][16] and plasmon [17,18] modes) and its valence band [10,19], was already discovered [12] before the current rush of publications.…”
Section: B Resultsmentioning
confidence: 99%
“…In the case of graphene on metals, the ability of intercalated chemical species to decouple graphene from the Ni(111), recovering the Dirac fermion character of its collective excitations (phonon [9,[14][15][16] and plasmon [17,18] modes) and its valence band [10,19], was already discovered [12] before the current rush of publications.…”
Section: B Resultsmentioning
confidence: 99%
“…all particles move coherently with a common frequency and wave-vector [171][172][173][174][175][176][177][178][179][180][181]. Plasmons are quantized wave-like excitations in a plasma, i.e.…”
Section: Sp Energymentioning
confidence: 99%
“…[14][15][16] These low-energy plasmons, which appear at mid-infrared and lower frequencies, should not be confused with the higher-energy π and σ plasmons that show up in most carbon allotropes, and that have been extensively studied through electron energy-loss spectroscopy (EELS) in fullerenes, 17,18 nanotubes, 19 and graphene. [20][21][22][23] These high-energy plasmons are not electrically tunable. We thus concentrate on electrically driven low-energy plasmons in graphene.…”
mentioning
confidence: 99%