We report the influence of excitation wavelength and pressure effects on the photoluminescence (PL) of silicon light-emitting diode material fabricated by boron ion implantation. The PL spectra show an anomalous increase in total intensity as temperature elevates, and this luminescence is found to be strongest with decreasing laser penetration depth away from the sample surface. The PL peak position shifts towards lower energy at a rate of -14 meV/GPa with increasing pressure. This rate agrees with earlier optical measurements on the band-edge absorption of silicon, confirming that this luminescence is closely related to phonon-assisted indirect band gap transitions.