Photochemical decarbonylation of Ph2 Ge[Fe(CO)2 (π-C5H5)]2 and analogous compounds

Cleland, A. J.; Fieldhouse, S. A.; Freeland, Brian; O’Brien, Richard

doi:10.1016/s0022-328x(00)80149-7

Cited by 23 publications

(2 citation statements)

References 17 publications

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“…The supernate was chromatographed over Florisil (CH2C12 eluent) to give several fractions. The only fraction identified was the fust, which gave a trace amount of brown crystals whose spectral properties are consistent with their formulation q,q-bis(dimethylgermylene)-bis(cyclopentadienyldicarbonylchromium), 13. The mass spectrum (165°, 20 eV) shows a parent molecule ion at m/e 552 (/ = 25) and stepwise loss of four carbonyls.…”

Section: Methodsmentioning

confidence: 80%

“…The chromium and molybdenum complexes CpM(CO)3-Ge(Cl)Me2 (12 and 20) decompose extensively upon photolysis. However, low yields of the bis(germylene) complexes, 13 and 21, could be realized from the complex reaction mixtures. The spectral data for these compounds are consistent with trans-bridged structures.27 It is interesting that the iron complexes 2 and 20 prefer the cis configuration while (26) G. L. Simon and L. F. Dahl, J. Amer.…”

Section: Resultsmentioning

confidence: 99%

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