PhenylN-phenylcarbamate

Abstract

In the title compound, C13H11NO2, the aromatic rings are oriented at a dihedral angle of 42.52 (12)°. The crystal structure is stabilized by inter­molecular N—H⋯O hydrogen bonds, which form infinite one-dimensional polymeric chains extending along the a axis. C—H⋯π inter­actions between the aromatic rings are also present.

Crystal structure of phenyl N-(3,5-dimethylphenyl)carbamate

“…Among these structures there are reports of two Pna2 1 polymorphs of phenyl phenylcarbamate itself, viz. YEHPOQ (Lehr et al, 2001) and YEHPOQ01 (Shahwar et al, 2009a), and those of phenyl (4methylphenyl)carbamate (YOVHOH; Bao et al, 2009) and phenyl(2-methylphenyl)carbamate (YOVLIF; Shahwar et al, 2009b). The conformations of all four reported molecules are different.…”

Crystal structures of 4-chlorophenylN-(3,5-dinitrophenyl)carbamate and phenylN-(3,5-dinitrophenyl)carbamate

“…A search of the Cambridge Structural Database (Version 5.36, February 2015; Groom & Allen, 2014) for phenyl N-phenylcarbamate gave 16 hits for similar compounds, including two orthorhombic poylmorphs of phenyl N-phenylcarbamate itself (YEHPOQ: Lehr et al, 2001;YEHPOQ01;Shahwar et al, 2009). In the first polymorph (YEHPOQ), the phenyl rings are inclined to one another by 25.76 , while in the latter (YEHPOQ01) the equivalent dihedral angle is 42.50 .…”

PhenylN-cyclohexylcarbamate

“…(2010). E66, o22 The crystal structures of (II) phenyl piperidine-1-carboxylate (Shahwar et al, 2010), (III) phenyl N-(2-methylphenyl)carbamate (Shahwar et al, 2009a) and (IV) phenyl N-phenylcarbamate (Shahwar et al, 2009b) have been reported by us.…”