Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds and Ionic Liquids. Sublimation, Vaporization, and Fusion Enthalpies from 1880 to 2015. Part 2. C11–C192

Abstract

The second part of this compendium concludes with a collection of phase change enthalpies of organic molecules inclusive of C11–C192 reported over the period 1880–2015. Also included are phase change enthalpies including fusion, vaporization, and sublimation enthalpies for organometallic, ionic liquids, and a few inorganic compounds. Paper I of this compendium, published separately, includes organic compounds from C1 to C10 and describes a group additivity method for evaluating solid, liquid, and gas phase heat capacities as well as temperature adjustments of phase changes. Paper II of this compendium also includes an updated version of a group additivity method for evaluating total phase change entropies which together with the fusion temperature can be useful in estimating total phase change enthalpies. Other uses include application in identifying potential substances that either form liquid or plastic crystals or exhibit additional phase changes such as undetected solid–solid transitions or behave anisotropically in the liquid state.

Experimental and modeling studies of binary organic eutectic systems to be used as stabilizers for nitrate esters-based energetic materials

“…The data have been used to extrapolate the melting properties values to b ¼ 0 K min À1 heating rate. As shown in the recent compilation by Acree and Chickos [10], the obtained experimental data, as well as those available in the literature, are listed in Table 2. The melting properties values are found generally in good agreement with the published data [7,9,11e18].…”

Potential new reference materials for caloric measurements on PCM

“…It comprises C12, C14, C16, and C18. In Tables 2-5 typical values from the NIST Chemistry WebBook are presented; further data can be found in a review by Acree and Chickos [41].…”

Interactions of amphiphiles with plasticisers used in polymers: Understanding the basis of health and environmental challenges

“…This transition enthalpy, in turn, is strongly correlated with molecular mass or molecular size in homologous series of compounds with similar chemistry. Acree and Chickos have provided extensive recent reviews of enthalpies of phase change that include data for a number of materials that are used as plasticisers [27,28]. A substantial but older list of vapour pressures and their correlation with ΔH vap was provided by Thomsen and Carlsen [29].…”