Pd/Cu‐free Heck and Sonogashira coupling reactions applying cobalt nanoparticles supported on multifunctional porous organic hybrid

Hajipour, Abdol R.; Khorsandi, Zahra

doi:10.1002/aoc.5398

Cited by 19 publications

(4 citation statements)

References 62 publications

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“…Recently, the synthesis of porous organic polymers (POP) using a facile low‐temperature strategy was reported for the first time by the group led by Hajipour [62] . Initially Imine‐POP was prepared.…”

Section: Cobalt‐catalyzed Reactionsmentioning

confidence: 99%

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Low‐Cost Transition Metal‐Catalyzed Heck‐Type Reactions: An Overview

2022

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Heck coupling has emerged as an effective and powerful tool for CÀ C bond formations, with applications in academic and industrial grounds. The conventional Mizoroki-Heck reaction employed expensive Pd based catalysts, however, developments to meet low-cost replacements to Pd is relevant from a sustainable point of view. Heck-type couplings involving costeffective transition metals such as Fe, Co, Ni, and Cu have been established in the recent decades. Herein, we have comprehended the developments in low-cost transition metal-catalyzed Heck couplings covering the literature from 2016.

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Section: Cobalt‐catalyzed Reactionsmentioning

confidence: 99%

“…Recently, the synthesis of porous organic polymers (POP) using a facile low-temperature strategy was reported for the first time by the group led by Hajipour. [62] Initially Imine-POP was prepared. Immobilizing Co species onto imine-POP resulted in the heterogeneous cobalt catalyst, Co@imine-POP.…”

Section: Cobalt-catalyzed Reactionsmentioning

confidence: 99%

Low‐Cost Transition Metal‐Catalyzed Heck‐Type Reactions: An Overview

2022

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“…A new heterogeneous cobalt catalyst (Co@imine-porous organic polymer) (Co@imine-POP) has been synthesized by immobilizing cobalt onto a nitrogen-rich porous organic polymer ( Scheme 20 ) [ 35 ]. Using scanning electron microscopy, the surface morphology of the catalyst was evaluated.…”

Section: Reviewmentioning

confidence: 99%

Recent developments and trends in the iron- and cobalt-catalyzed Sonogashira reactions

Amrutha¹,

Radhika²,

Anilkumar³

2022

Beilstein J. Org. Chem.

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Iron- and cobalt-catalyzed Sonogashira coupling reactions are becoming central areas of research in organic synthesis. Owing to their significant importance in the formation of carbon–carbon bonds, numerous green and nanoparticle protocols have emerged during the past decades. The non-toxic and inexpensive nature of catalysts gained much attention in recent times. In this context, their catalytic nature and activity in Sonogashira coupling reactions were well explored and compared. Most importantly, one of the highlights of this review is the emphasis given to green strategies. This is the first review on iron- and cobalt-catalyzed Sonogashira coupling reactions which comprehends literature up to 2020.

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“…These materials possess several highly desirable properties: pore topologies that possess long-range structural ordering, a uniform pore size, and high surface areas. Due to the typical advantages of the porous supports, the size control of the stabilized metal NPs and the selective reactions dependent on the pore size have been achieved [134][135][136][137][138][139][140][141][142][143][144][145][146][147][148][149][150][151].…”

Section: Porous Materialsmentioning

confidence: 99%

Recent Progress of Metal Nanoparticle Catalysts for C–C Bond Forming Reactions

Ohtaka¹

2021

Catalysts

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Over the past few decades, the use of transition metal nanoparticles (NPs) in catalysis has attracted much attention and their use in C–C bond forming reactions constitutes one of their most important applications. A huge variety of metal NPs, which have showed high catalytic activity for C–C bond forming reactions, have been developed up to now. Many kinds of stabilizers, such as inorganic materials, magnetically recoverable materials, porous materials, organic–inorganic composites, carbon materials, polymers, and surfactants have been utilized to develop metal NPs catalysts. This review classified and outlined the categories of metal NPs by the type of support.

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Pd/Cu‐free Heck and Sonogashira coupling reactions applying cobalt nanoparticles supported on multifunctional porous organic hybrid

Cited by 19 publications

References 62 publications

Low‐Cost Transition Metal‐Catalyzed Heck‐Type Reactions: An Overview

Low‐Cost Transition Metal‐Catalyzed Heck‐Type Reactions: An Overview

Recent developments and trends in the iron- and cobalt-catalyzed Sonogashira reactions

Recent Progress of Metal Nanoparticle Catalysts for C–C Bond Forming Reactions

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