Osmotic coefficients of aqueous lithium chloride and calcium chloride from their isopiestic ratio to sodium chloride at 50.degree.C

A Temperature-Dependent Thermodynamic Model Derived from Heat Capacity of Metal Chloride Aqueous Solutions

“…Although the limited experimental data of mean ion activity coefficient is available, the calculated values in this work are consistent with the results calculated from electromotive force measurements of galvanic cells by Staples . Moreover, the osmotic coefficient data at temperatures other than 298.15 K from Gilchrist, Davis, and Patil were compared with the calculated values. It can be found from Figure S2 that the calculated results at 303.15, 313.15, 328.15, and 343.15 K also agree with the reported values, respectively.…”

“…Heat Capacities at Constant Pressure (C P ) of CuCl 2 −H 2 O System with Different Temperatures and Molalities at 0.1 MPa afrom Gilchrist,9 Davis,22 and Patil23 were compared with the calculated values. It can be found from FigureS2that the calculated results at 303.15, 313.15, 328.15, and 343.15 K also agree with the reported values, respectively.…”

Vapor pressures and isopiestic molalities of concentrated CaCl2(aq), CaBr2(aq), and NaCl(aq) to T=523 K

“…A number of other experimental datasets [61][62][63][64][65][66][67][68][69][70][71][72] were used in part, used with very small weights, or not used at all in the final regression, due to either significant deviations from the data described above or to insufficient precision. Among these, the high temperature vapor pressure results, in particular those above 523.15 K to moderate concentrations were in general not precise enough to quantitatively improve the extrapolation of the present results combined with the model of Holmes et al [11].…”

Systematic Evaluation of Parameterization Approaches for the ePPC-SAFT Model for Aqueous Alkali Halide Solutions. II. Alkali Bromides, Iodides, Fluorides, And Lithium Halides

“…These data were evaluated in Ref [7]. The experimental data are from Ref [45,54,[223][224][225][226][227][228]. They are limited based on the ranges of the MIAC data, and are not used in the regression, but rather are used only for prediction.…”