Orthogonal-array dynamic molecular sieving of propylene/propane mixtures

Metal–organic framework‐derived phosphide nanomaterials for electrochemical applications

“…As porous ligand materials, metal–organic frameworks (MOFs) are composed of metal ions and cluster organics, which have been widely studied. As such, various characterization methods have shown that MOF materials have excellent frameworks and pore structures, 1 which make them attractive in fields like supercapacitors (SCs), chemical sensing, gas storage and separation, adsorption, biomedical applications, proton conduction, and drug delivery 2–35 . Compared with other ligand materials, MOF materials are deemed to be one of the promising materials in the nano feild of future in view of their excellent properties such as high porosity, large surface area, controllable structure, low density, and adjustable pore size 20,29,36–39 .…”

Flexible Metal–Organic Frameworks as CO2 Adsorbents en Route to Energy‐Efficient Carbon Capture

“…Researchers have made great strides in solving this problem by controlling the structure of MOFs to fabricate them with narrow channel windows for large selectivity and pore volume for large capacity, such as the case of JNU‐3. [ 19 ] The rational design of MOFs embodying such standards is not easy, and other universal methods remain needed. With the rise in circular carbon economy, balancing the carbon regeneration energy consumption, working capacity, and selectivity of MOFs is quite difficult.…”

Linker micro-regulation of a Hofmann-based metal–organic framework for efficient propylene/propane separation

“…Through linker modification, HAIM-301 preferentially adsorbed C 3 H 6 (3.2 mmol g −1 ) from mixtures with the complete exclusion of C 3 H 8 , which could be attributed to a distortion of the pores compared to their original form. Very recently, Li et al 40 fabricated JNU-3a with an orthogonal-array dynamic molecular pocket, which permitted highly efficient C 3 H 6 /C 3 H 8 separation with record C 3 H 6 productivity (34.2 L kg −1 ). Although several MOFs with unprecedented performance have been established, it is still an ongoing challenge to fabricate MOF adsorbents with robust stability for C 3 H 6 /C 3 H 8 separation through industrially viable synthesis methods (Fig.…”