2011
DOI: 10.1002/ejic.201100421
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Organic Nanostructures with Controllable Morphology Fabricated from Ferrocene–Porphyrin Derivatives: Effect of Metal–Ligand Coordination on the Morphology, Dimensions, and Semiconductor Properties of Self‐Assembled Nanostructures

Abstract: Two new ferrocene-porphyrin derivatives, namely 5,15-bis(ferrocenyl)-10,20-bis(4-nitrophenyl)porphyrin (1) and its nickel congener 5,15-bis(ferrocenyl)-10,20-bis(4-nitrophenyl)porphyrinatonickel (2) have been designed, synthesized, and characterized. Their self-assembly properties have been comparatively studied by electronic absorption and FTIR spectroscopy, TEM, SEM, XRD, and X-ray photoelectron spectroscopy (XPS). Metal-free 1 self-assembles into nanospheres with diameters in the range of 30-50 nm, de-

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Cited by 7 publications
(1 citation statement)
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“…The XRD spectrum for pristine MWCNTs showed a prominent peak at 2θ = 25.68°corresponding to the (002) plane of the graphitic structure [25]. For ZnBCBTP@MWCNTs, an additional peak at 2θ = 28.03°was found, which was due to the π-π interaction of adjacent stacked porphyrin molecules in the direction perpendicular to the porphyrin rings [26]. As a result, non-covalent anchoring of ZnBCBTP onto MWCNTs through π-π stacking was achieved.…”
Section: Structure and Morphology Characterizationmentioning
confidence: 97%
“…The XRD spectrum for pristine MWCNTs showed a prominent peak at 2θ = 25.68°corresponding to the (002) plane of the graphitic structure [25]. For ZnBCBTP@MWCNTs, an additional peak at 2θ = 28.03°was found, which was due to the π-π interaction of adjacent stacked porphyrin molecules in the direction perpendicular to the porphyrin rings [26]. As a result, non-covalent anchoring of ZnBCBTP onto MWCNTs through π-π stacking was achieved.…”
Section: Structure and Morphology Characterizationmentioning
confidence: 97%