The slow buildup of photoconductance due to a peak centered at 1.13 eV below the conduction band in n-type 6H–SiC samples has been studied using optical admittance spectroscopy. The background doping of the samples ranges from 3.2×1015 cm−3 to 2×1018 cm−3. The results indicate that the carriers responsible for the observed conductance are excited from defect levels that are energetically close. The photoconductance transients are completely described by a sum of two exponential expressions. The relevant parameters, α1,α2,Gmax(1), and Gmax(2), are determined as functions of temperatures. The background doping ND-NA has no effect on the conductance buildup process, this indicates that the nitrogen donors play no role either in the formation of the defect or in the buildup process of the photoconductance.