New β-diketon-(2-phenylethyl)imine Schiff base chelates of copper(II), nickel(II) and cobalt(III) and their electrophilic substitution products

Samath, S. Abdul; Raman, Natarajan; Jeyasubramanian, K.; Ramalingam, S.

doi:10.1016/s0277-5387(00)83783-3

Cited by 8 publications

(2 citation statements)

References 8 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Lower vibration bands for C@C and C@N bonds may be due to the pseudo aromatic chelating structure in which the p-electrons are somewhat delocalized. These are in agreement with previous result [18]. m(M-N) vibration bands are visible in the range 470-430 cm À1 .…”

Section: Synthesis and Characterizationsupporting

confidence: 94%

Synthesis, characterization and luminescence study of dimethyl(β-ketoiminato)gallium (-indium) complexes: crystal structure of dimethyl[1-phenyl-3-N-(4-methoxyphenylimino)-1-butanonato]gallium

Shen¹,

Han²,

Gu³

et al. 2004

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

Section: Synthesis and Characterizationsupporting

confidence: 94%

Synthesis, characterization and luminescence study of dimethyl(β-ketoiminato)gallium (-indium) complexes: crystal structure of dimethyl[1-phenyl-3-N-(4-methoxyphenylimino)-1-butanonato]gallium

Shen¹,

Han²,

Gu³

et al. 2004

Journal of Organometallic Chemistry

View full text Add to dashboard Cite

“…Interestingly, some Co(III) complexes with ligated imine groups have been synthesized via oxidation of their Co(II) counterparts by careful addition of H 2 O 2 . These studies did not report any reaction of the ligand frame with the oxidant and in all cases, the Co(III) Schiff base complexes were isolated as the major products.…”

Section: Resultsmentioning

confidence: 99%

Conversion of Azomethine Moiety to Carboxamido Group at Cobalt(III) Center in Model Complexes of Co-Containing Nitrile Hydratase

2001

View full text Add to dashboard Cite

The Co(III) complex of the Schiff base ligand N-2-mercaptophenyl-2'-pyridylmethyl-enimine (PyASH), namely, [Co(PyAS)(2)]Cl (1), has been synthesized via an improved method and its structure has been determined by X-ray crystallography. The two deprotonated ligands are arranged in mer configuration around the Co(III) center and the overall coordination geometry is octahedral. The coordinated azomethine function in 1 is rapidly converted into carboxamido group upon reaction with OH(-). The product is the bis carboxamido complex (Et(4)N)[Co(PyPepS)(2)] (2), reported by us previously. Reaction of H(2)O(2) with 1 in DMF affords [Co(PyASO(2))(PyPepSO(2))] (3), a species with mixed imine and carboxamido-N donor centers as well as S-bound sulfinates. Further reaction with H(2)O(2) in the presence of NaClO(4) converts 3 into the previously reported bis carboxamido/sulfinato complex Na[Co(PyPepSO(2))(2)] (4). The reaction conditions for the various transformation reactions for complexes 1-4 and the structure of 3 are also reported. The mechanism of the -CH=NR + [O] --> -C(=O)NHR transformation has been discussed. The reactions reported here provide convenient alternate routes for the syntheses of Co(III) complexes with coordinated carboxamide, thiolate, and/or sulfinate donors as models for the Co-site in the Co-containing nitrile hydratase(s).

show abstract

Chemical Vapor Deposition of Assorted Metals

Hampden‐Smith

Kodas

1994

The Chemistry of Metal CVD

View full text Add to dashboard Cite

New β-diketon-(2-phenylethyl)imine Schiff base chelates of copper(II), nickel(II) and cobalt(III) and their electrophilic substitution products

Cited by 8 publications

References 8 publications

Synthesis, characterization and luminescence study of dimethyl(β-ketoiminato)gallium (-indium) complexes: crystal structure of dimethyl[1-phenyl-3-N-(4-methoxyphenylimino)-1-butanonato]gallium

Synthesis, characterization and luminescence study of dimethyl(β-ketoiminato)gallium (-indium) complexes: crystal structure of dimethyl[1-phenyl-3-N-(4-methoxyphenylimino)-1-butanonato]gallium

Conversion of Azomethine Moiety to Carboxamido Group at Cobalt(III) Center in Model Complexes of Co-Containing Nitrile Hydratase

Chemical Vapor Deposition of Assorted Metals

Contact Info

Product

Resources

About