The criteria for the formation of a CuAlO 2 reaction phase at the Cu/Al 2 O 3 interface are explored. Oxygen solutes up to 2 wt% were introduced into the copper first. The bonding was carried out at 1075°C. The reaction phase was observed only when the oxygen solute in copper before bonding was higher than 1.3 wt%. The CuAlO 2 phase is polycrystalline and covers only part of the interface. The CuAlO 2 grains interact with the crack, which improves the interface strength. As CuAlO 2 is not continuous at the interface, the thermal conductivity of the Al 2 O 3 /Cu/Al 2 O 3 laminate is affected little.