“…It has been found that the addition of other elements such as silicon (Si) in MeN systems can have profound effects on their mechanical, chemical and tribological properties [11,14,[221][222][223][224][225]. These changes have been explained by two main mechanisms: the formation of a nanocomposite microstructure formed by the segregation of MeN grains separated by a monolayer thick SiN x matrix [14,221,223] and solid solution hardening [11,222] due to the substitution of Me atoms by Si in the MeN lattice.…”