“…In particular, the ferroelectric field effect transistors (FET)-type memory [1][2][3], in which the gate with metal/ferroelectric/semiconductor (MFS) structure is controlled by the spontaneous polarization of ferroelectric materials, is recognized to be promising candidate due to its potential advantages of fast switching, tolerance against radiation, nondestructive readout and high density for nonvolatile memory application. However, the main difficult in realizing these FET-type memory devices is to obtain a reliable ferroelectric/Si interface, because of the interface reaction during fabrication, which results in the carrier injection at the interface, and lower retention, for example, it is well know that Pb(Zr, Ti)O 3 (PZT) can easily react with Si and the interdiffusion of Pb and Si at the PZT/Si interface occurs even at a temperature as low as 500 • C [4,5], hence, to overcome these difficulties, insulating buffer layers such as yttria-stablized zirconia (YSZ) [6], CeO 2 [7,8], MgO [9], and SrTiO 3 [10] films are usually inserted between the ferroelectric layer and silicon substrates to form a metal/ferroelectric/insulator/semiconductor (MFIS) structure, but it was found that these buffer layer have large absorption current due to the high density of crystalline defects or carrier traps existing in the interface of Si and buffer.…”